Remarkable effects of counter ions on scandium ion-promoted electron transfer reactions

Literature Information

Publication Date 2003-04-02
DOI 10.1039/B300543G
Impact Factor 6.222
Authors

Junpei Yuasa, Tomoyoshi Suenobu, Kei Ohkubo, Shunichi Fukuzumi


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Abstract

Scandium ion-promoted electron transfer reactions of p-benzoquinone are remarkably accelerated when tetrakis(pentafluorophenyl)borate anion is used instead of trifluoromethanesulfonate anion as the counter anion of scandium ion. Only a catalytic amount of scandium borate salt (Sc[B(C6F5)4]3) accelerates significantly the Diels–Alder reaction of 9,10-dimethylanthracene with p-benzoquinone, which proceeds via Sc3+-promoted electron transfer from the anthracene to p-benzoquinone.

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