High tetraalkylaluminate fluxionality in half-sandwich complexes of the trivalent rare-earth metals
Literature Information
Reiner Anwander, Michael G. Klimpel, H. Martin Dietrich, Dmitry J. Shorokhov, Wolfgang Scherer
Steric factors govern the formation of half-sandwich complexes (C5Me4R)Ln[N(SiHMe2)2]2 according to acid–base reactions utilising Ln[N(SiHMe2)2]3(thf)2 and substituted cyclopentadienes. Subsequent trimethylaluminium-promoted silylamide elimination produces the first half-sandwich bis(tetramethylaluminate) complexes (C5Me4R)Ln(AlMe4)2.
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