The phenolortho-oxygenation by mononuclear copper(i) complexes requires a dinuclear μ-η2∶η2-peroxodicopper(ii) complex rather than mononuclear CuO2 species

Literature Information

Publication Date 2003-02-17
DOI 10.1039/B212683D
Impact Factor 6.222
Authors

Giuseppe Battaini, Marco De Carolis, Enrico Monzani, Felix Tuczek, Luigi Casella


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Abstract

The mononuclear complex [Cu(L)]+ performs the ortho-oxygenation of an exogeneous phenol through the formation of a dinuclear μ-η2∶η2-peroxodicopper(II) intermediate, which is so far the only type of copper–dioxygen complex that mediates the tyrosinase monophenolase reaction.

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