Unexpected coupling between an η5-indenyl ligand and alkenyl-vinylidene fragments: synthesis of unprecedented (η6-indene)ruthenium(ii) metallacycles
Literature Information
Victorio Cadierno, Salvador Conejero, Josefina Díez, M. Pilar Gamasa, José Gimeno, Santiago García-Granda
Vinylidene complexes [Ru{CC(H)CR1R2CH2C(Me)CH2}(η5-C9H7)(PPh3)2][BF4] undergo an intramolecular coupling between the alkenyl-vinylidene fragment and the η5-indenyl ligand to afford indene-metallacyclic compounds (6a,b) in which the resulting functionalised indene group is η6-coordinated to the metal.
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