Unexpected coupling between an η5-indenyl ligand and alkenyl-vinylidene fragments: synthesis of unprecedented (η6-indene)ruthenium(ii) metallacycles

Literature Information

Publication Date 2003-02-28
DOI 10.1039/B212406H
Impact Factor 6.222
Authors

Victorio Cadierno, Salvador Conejero, Josefina Díez, M. Pilar Gamasa, José Gimeno, Santiago García-Granda


View Original

Abstract

Vinylidene complexes [Ru{CC(H)CR1R2CH2C(Me)CH2}(η5-C9H7)(PPh3)2][BF4] undergo an intramolecular coupling between the alkenyl-vinylidene fragment and the η5-indenyl ligand to afford indene-metallacyclic compounds (6a,b) in which the resulting functionalised indene group is η6-coordinated to the metal.

Related Literature

Front cover

2022-02-01 Cover

DOI: 10.1039/D2SE90008D

Transparent porous polymer sheets for efficient product separation in solar water splitting

Ciler Özen, Keisuke Obata, Peter Bogdanoff, Fatwa F. Abdi

2021-12-09 Paper

DOI: 10.1039/D1SE01475G

Method for fabricating highly crystalline polyvinylidene fluoride for piezoelectric energy-harvesting and vibration sensor applications

Nirmal Prashanth Maria Joseph Raj, Abisegapriyan KS, Gaurav Khandelwal, Sang-Jae Kim

2021-12-14 Paper

DOI: 10.1039/D1SE01139A

Decoding the charge carrier dynamics in triple cation-based perovskite solar cells

Mohd Taukeer Khan, Naveen Harindu Hemasiri

2021-10-26 Paper

DOI: 10.1039/D1SE01398J

Contents list

2021-10-26 Front/Back Matter

DOI: 10.1039/D1SE90075G

Opportunities in Na/K [hexacyanoferrate] frameworks for sustainable non-aqueous Na+/K+ batteries

Ashwani Tyagi, Nagmani, Sreeraj Puravankara

2021-12-03 Review Article

DOI: 10.1039/D1SE01653A

Fast and scale-up synthesis of amorphous C,N co-doped mesoporous Co-based phosphates as advanced electrodes for supercapacitors and water oxidation

Zheng-Han Guo, Jie-Ying Lin, Pei-Ru Chen, Kai-Qin Ou, Xiang-Ya Xu, Jin-Kun Li, Sai Huang, Xin-Xin Sang, Jing-Cheng Liu, Jun-Ling Song

2021-09-28 Paper

DOI: 10.1039/D1SE01313K

High hydrogen release catalytic activity by quasi-MOFs prepared via post-synthetic pore engineering

Minoo Bagheri, Mohammad Yaser Masoomi, Esther Domínguez, Hermenegildo García

2021-07-20 Paper

DOI: 10.1039/D1SE00661D

You might also like

Compound Q&A

What precautions should be taken when handling 2-Methyl-2-propanyl 5-amino-2-thiophenecarboxylate (CAS: 1498311-57-1)?

When handling 2-Methyl-2-propanyl 5-amino-2-thiophenecarboxylate (CAS: 1498311-5...

1498311-57-12-Methyl-2-propanyl ...
Compound Q&A

What are the physical and chemical properties of 5-Bromo-1,2-dichloro-3-fluorobenzene (CAS: 1000572-93-9)?

5-Bromo-1,2-dichloro-3-fluorobenzene (CAS: 1000572-93-9) is a crystalline solid ...

1000572-93-95-Bromo-1,2-dichloro...
Compound Q&A

How should (2R)-2-Amino-2-(4-bromophenyl)ethanol (CAS: 354153-64-3) be stored?

(2R)-2-Amino-2-(4-bromophenyl)ethanol (CAS: 354153-64-3) should be stored in a c...

354153-64-3(2R)-2-Amino-2-(4-br...
Compound Q&A

What regulatory guidelines apply to Methyl 4-(aminomethyl)tetrahydro-2H-pyran-4-carboxylate hydrochloride (CAS: 362707-24-2)?

Methyl 4-(aminomethyl)tetrahydro-2H-pyran-4-carboxylate hydrochloride (CAS: 3627...

362707-24-2Methyl 4-(aminomethy...
Compound Q&A

What are the main uses of 1,4-dimethyl-1H-pyrazole-5-sulfonyl chloride (CAS: 1174834-52-6)?

1,4-Dimethyl-1H-pyrazole-5-sulfonyl chloride is primarily used as an intermediat...

1174834-52-61,4-dimethyl-1H-pyra...
Compound Q&A

Is Dinaphtho[1,2-b:2',1'-d]furan (CAS: 239-69-0) safe?

Dinaphtho[1,2-b:2',1'-d]furan is generally safe when handled with appropriate pe...

239-69-0Dinaphtho[1,2-b:2',1...
Compound Q&A

What is the market or research trend for 7-Methyl-7,9-dihydro-1H-purine-2,6,8(3H)-trione (CAS: 612-37-3)?

The market for 7-Methyl-7,9-dihydro-1H-purine-2,6,8(3H)-trione (CAS: 612-37-3) i...

612-37-37-Methyl-7,9-dihydro...
Compound Q&A

What are the physical and chemical properties of 2-(4-Chlorophenyl)malonaldehyde (CAS: 205676-17-1)?

2-(4-Chlorophenyl)malonaldehyde (CAS: 205676-17-1) is a colorless or light yello...

205676-17-12-(4-Chlorophenyl)ma...
Compound Q&A

How is 2-Methylchrysene (CAS: 3351-32-4) typically synthesized?

2-Methylchrysene (CAS: 3351-32-4) is typically synthesized via the reaction of c...

3351-32-42-Methylchrysene
Compound Q&A

Is N-(6-aminopyrimidin-4-yl)acetamide (CAS: 89533-23-3) safe?

N-(6-aminopyrimidin-4-yl)acetamide (CAS: 89533-23-3) is generally considered saf...

89533-23-3N-(6-aminopyrimidin-...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.