Dopant incorporation into garnet solid solutions—a breakdown of Goldschmidt’s first rule
Literature Information
Publication Date
2003-02-20
DOI
10.1039/B211249C
Impact Factor
6.222
Authors
N. L. Allan, J. D. Blundy, M. Yu. Lavrentiev, B. R. Lucas, J. A. Purton
View Original
Abstract
Atomistic simulations suggest trace elements are more soluble in a 50∶50 pyrope (Mg3Al2Si3O12)–grossular (Ca3Al2Si3O12) garnet mixture than in either end-member; consistent with partitioning experiments, and, contrary to Goldschmidt’s first rule, large trace element cations may substitute for Mg2+, small trace elements for Ca2+.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
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Recommended Compounds
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(3E)-3-[4-Hydroxy-3,5-bis(2-methyl-2-propanyl)benzylidene]dihydro-2(3H)-furanone
CAS Number:
102271-49-8
Molecular Formula:
C19H26O3
![5,7-Dihydroxy-3-(4-hydroxyphenyl)-6-[(1R,6R)-3-methyl-6-prop-1-en-2-ylcyclohex-2-en-1-yl]chromen-4-one structure](https://static.chemtradehub.com/structs/191/1914963-20-4-2b05.webp "5,7-Dihydroxy-3-(4-hydroxyphenyl)-6-[(1R,6R)-3-methyl-6-prop-1-en-2-ylcyclohex-2-en-1-yl]chromen-4-one structure")
5,7-Dihydroxy-3-(4-hydroxyphenyl)-6-[(1R,6R)-3-methyl-6-prop-1-en-2-ylcyclohex-2-en-1-yl]chromen-4-one
CAS Number:
1914963-20-4
Molecular Formula:
C25H24O5
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