Dopant incorporation into garnet solid solutions—a breakdown of Goldschmidt’s first rule

Literature Information

Publication Date 2003-02-20
DOI 10.1039/B211249C
Impact Factor 6.222
Authors

N. L. Allan, J. D. Blundy, M. Yu. Lavrentiev, B. R. Lucas, J. A. Purton


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Abstract

Atomistic simulations suggest trace elements are more soluble in a 50∶50 pyrope (Mg3Al2Si3O12)–grossular (Ca3Al2Si3O12) garnet mixture than in either end-member; consistent with partitioning experiments, and, contrary to Goldschmidt’s first rule, large trace element cations may substitute for Mg2+, small trace elements for Ca2+.

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