Dopant incorporation into garnet solid solutions—a breakdown of Goldschmidt’s first rule
Literature Information
N. L. Allan, J. D. Blundy, M. Yu. Lavrentiev, B. R. Lucas, J. A. Purton
Atomistic simulations suggest trace elements are more soluble in a 50∶50 pyrope (Mg3Al2Si3O12)–grossular (Ca3Al2Si3O12) garnet mixture than in either end-member; consistent with partitioning experiments, and, contrary to Goldschmidt’s first rule, large trace element cations may substitute for Mg2+, small trace elements for Ca2+.
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