Solvent dynamical effects on the electron self-exchange rate of the TEMPO˙/TEMPO+ couple (TEMPO = 2,2,6,6-tetramethyl-1-piperidinyloxy radical) Part I. ESR-linebroadening measurements at T = 298 K

Literature Information

Publication Date 2002-10-03
DOI 10.1039/B206313A
Impact Factor 3.676
Authors

Guenter Grampp, Kenneth Rasmussen


View Original

Abstract

Rate constants of the electron self-exchange for the TEMPO˙/TEMPO+ couple were measured in acetonitrile, benzonitrile, deuterium oxide, propylene carbonate, THF and water at T = 298 K. The experimental rate constants cover a range of 0.88 × 108 ⩽ ket ⩽ 5.0 × 108 M−1 s−1 and clearly show a solvent dynamical “friction” effect controlled by the longitudinal relaxation time of the solvent τL.

Related Literature

Poly(tetrafluoroethylene-co-perfluorovinyl ether sulfonamide) for anion exchange membranes

Xundao Liu, Hongrong Gao, Xiaohong Chen, Yong Hu, Hong Li, Yongming Zhang

2016-03-30 Paper

DOI: 10.1039/C6PY00036C

Back cover

Cover

DOI: 10.1039/C5PY90095F

Construction of redox/pH dual stimuli-responsive PEGylated polymeric micelles for intracellular doxorubicin delivery in liver cancer

Hong Yu Yang, Moon-Sun Jang, Guang Hui Gao, Jung Hee Lee, Doo Sung Lee

2016-01-27 Paper

DOI: 10.1039/C5PY01808K

A cross-linked supramolecular polymer constructed from pillar[5]arene and porphyrine via host–guest interactions

Nana Sun, Jianzhuang Jiang

2015-06-08 Communication

DOI: 10.1039/C5PY00683J

Synthesis of perfectly alternating copolymers for polymers of intrinsic microporosity

Jian Zhang, Ralph Cooney, Qiang Fu, Greg G. Qiao, Sylvie Thomas, Tim C. Merkel

2015-06-03 Communication

DOI: 10.1039/C5PY00570A

Antimicrobial coatings against biofilm formation: the unexpected balance between antifouling and bactericidal behavior

Zhi Xiang Voo, Majad Khan, Qingxing Xu, Karthikeyan Narayanan, Brandon W. J. Ng, Raidah Bte Ahmad, James L. Hedrick, Yi Yan Yang

2015-11-26 Paper

DOI: 10.1039/C5PY01718A

Cyclohexyl-substituted poly(phosphonate)-copolymers with adjustable glass transition temperatures

Thomas Wolf, Johannes Naß, Frederik R. Wurm

2016-03-30 Communication

DOI: 10.1039/C6PY00358C

Back cover

Cover

DOI: 10.1039/C5PY90107C

You might also like

Compound Q&A

What are the main uses of (5-Sulfamoyl-3-pyridinyl)boronic acid (CAS: 951233-61-7)?

(5-Sulfamoyl-3-pyridinyl)boronic acid is primarily used in chemical synthesis, p...

951233-61-7(5-Sulfamoyl-3-pyrid...
Compound Q&A

How is Benzyl 2-methyl-2-(methylsulfonyl)-4-pentenoate (CAS: 1942858-50-5) typically synthesized?

Benzyl 2-methyl-2-(methylsulfonyl)-4-pentenoate is typically synthesized via est...

1942858-50-5Benzyl 2-methyl-2-(m...
Compound Q&A

What precautions should be taken when handling 8-Fluoroquinolin-6-ol (CAS: 209353-22-0)?

When handling 8-Fluoroquinolin-6-ol (CAS: 209353-22-0), it is important to use p...

209353-22-08-Fluoroquinolin-6-o...
Compound Q&A

What are the physical and chemical properties of 1,3-Dibromo-5-(2-methyl-2-propanyl)benzene (CAS: 129316-09-2)?

1,3-Dibromo-5-(2-methyl-2-propanyl)benzene (CAS: 129316-09-2) is a crystalline c...

129316-09-21,3-Dibromo-5-(2-met...
Compound Q&A

What industries use Ethyl 7-chloro-4-oxo-1-(1,3-thiazol-2-yl)-1,4-dihydro-1,8-naphthyridine-3-carboxylate (CAS: 174726-87-5)?

Ethyl 7-chloro-4-oxo-1-(1,3-thiazol-2-yl)-1,4-dihydro-1,8-naphthyridine-3-carbox...

174726-87-5Ethyl 7-chloro-4-oxo...
Compound Q&A

What precautions should be taken when handling Delta-7-Avenasterol (CAS: 23290-26-8)?

When handling Delta-7-Avenasterol (CAS: 23290-26-8), it is important to wear app...

23290-26-8Delta-7-Avenasterol
872992-20-6N-({(5R)-3-[3-Fluoro...
Compound Q&A

What precautions should be taken when handling 2-Methyl-2-proanyl 4-[(2-aminophenyl)amino]-1-piperidinecarboxylate (CAS: 79099-00-6)?

When handling 2-Methyl-2-proanyl 4-[(2-aminophenyl)amino]-1-piperidinecarboxylat...

79099-00-62-Methyl-2-propanyl ...
Compound Q&A

What is N-Methyl-4-chlorobenzylamine hydrochloride (CAS: 65542-24-7)?

N-Methyl-4-chlorobenzylamine hydrochloride (CAS: 65542-24-7) is a organic compou...

65542-24-7N-Methyl-4-chloroben...
Compound Q&A

Is [2-(Dodecyloxy)ethoxy]acetic acid (CAS: 27306-90-7) safe?

[2-(Dodecyloxy)ethoxy]acetic acid (CAS: 27306-90-7) is generally considered safe...

27306-90-7[2-(Dodecyloxy)ethox...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.