Solvent dynamical effects on the electron self-exchange rate of the TEMPO˙/TEMPO+ couple (TEMPO = 2,2,6,6-tetramethyl-1-piperidinyloxy radical) Part I. ESR-linebroadening measurements at T = 298 K
Literature Information
Guenter Grampp, Kenneth Rasmussen
Rate constants of the electron self-exchange for the TEMPO˙/TEMPO+ couple were measured in acetonitrile, benzonitrile, deuterium oxide, propylene carbonate, THF and water at T = 298 K. The experimental rate constants cover a range of 0.88 × 108 ⩽ ket ⩽ 5.0 × 108 M−1 s−1 and clearly show a solvent dynamical “friction” effect controlled by the longitudinal relaxation time of the solvent τL.
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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![[3-Fluoro-4-(1-pyrrolidinylcarbonyl)phenyl]boronic acid structure [3-Fluoro-4-(1-pyrrolidinylcarbonyl)phenyl]boronic acid structure](https://static.chemtradehub.com/structs/874/874289-09-5-e3d4.webp)

