Fluid phase diagrams of ternary systems with one volatile component and immiscibility in two of the constituent binary mixtures

Literature Information

Publication Date 2002-02-27
DOI 10.1039/B109275H
Impact Factor 3.676
Authors


View Original

Abstract

Four types of fluid phase diagram where the critical curves and immiscibility regions are not intersected by crystallization surfaces are selected as the main types of fluid phase behavior in binary mixtures. These types are used as a starting point for the systematic classification of the main types of binary complete phase diagram, describing any equilibria with liquid, gas and solid phases over a wide range of temperatures and pressures, by the method of continuous topological transformation. This method and the classification of binary phase diagrams, containing the boundary version phase diagrams with ternary nonvariant points, are used as a quasi-binary approach to derive the main types of fluid phase behavior for ternary mixtures with one volatile component and immiscibility in two of the constituent binary subsystems. In such ternary systems there are six classes distinguished by the types of fluid phase behavior in the binary subsystems. A wide variety of ternary fluid phase diagrams, obtained either by a transformation of the topological types or by changing the location of nonvariant points without transformation of topological types, is discussed.

Related Literature

Insights into DNA catalysis from structural and functional studies of the 8-17 DNAzyme

Marjorie Cepeda-Plaza, Alessio Peracchi

2020-01-28 Review Article

DOI: 10.1039/C9OB02453K

Visible light induced 3-position-selective addition of arylpropiolic acids with ethers via C(sp3)–H functionalization

Zi-juan Wan, Xiao-feng Yuan, Jun Luo

2020-04-07 Communication

DOI: 10.1039/D0OB00480D

Total synthesis of nafuredin B

Gour Hari Mandal, Dhiman Saha, Rajib Kumar Goswami

2020-03-05 Paper

DOI: 10.1039/D0OB00370K

Tandem transformations and multicomponent reactions utilizing alcohols following dehydrogenation strategy

Bhaskar Paul, Milan Maji, Kaushik Chakrabarti, Sabuj Kundu

2020-02-17 Review Article

DOI: 10.1039/C9OB02760B

Front cover

Cover

DOI: 10.1039/C9OB90185J

A Selectfluor-promoted oxidative reaction of disulfides and amines: access to sulfinamides

Jiang Liu, Romana Pajkert, Gerd-Volker Röschenthaler, Jianlin Han

2020-05-06 Paper

DOI: 10.1039/D0OB00720J

Examination of pinanediol–boronic acid ester formation in aqueous media: relevance to the relative stability of trigonal and tetrahedral boronate esters

Mayte A. Martínez-Aguirre, Marcos Flores-Alamo, Felipe Medrano, Anatoly K. Yatsimirsky

2020-03-18 Paper

DOI: 10.1039/D0OB00201A

You might also like

Compound Q&A

What regulatory guidelines apply to 6-Bromo-2-methylimidazo[1,2-a]pyrimidine (CAS: 1111638-05-1)?

6-Bromo-2-methylimidazo[1,2-a]pyrimidine (CAS: 1111638-05-1) falls under various...

1111638-05-16-Bromo-2-methylimid...
Compound Q&A

Are there alternatives to 1-Pyrrolidineethanol, β-methyl-α-phenyl-, (αS,βR) (CAS: 123620-80-4) in synthesis?

While there are no direct alternatives, similar compounds like 1-Pyrrolidineetha...

123620-80-41-Pyrrolidineethanol...
Compound Q&A

Is 4-Methyl-2,6-bis(2-methyl-2-propanyl)phenyl methylcarbamate (CAS: 1918-11-2) safe?

4-Methyl-2,6-bis(2-methyl-2-propanyl)phenyl methylcarbamate (CAS: 1918-11-2) is ...

1918-11-24-Methyl-2,6-bis(2-m...
Compound Q&A

How should 2-(3-Bromo-4-fluorophenyl)-1,3-dioxolane (CAS: 77771-04-1) be stored?

2-(3-Bromo-4-fluorophenyl)-1,3-dioxolane (CAS: 77771-04-1) should be stored in a...

77771-04-12-(3-Bromo-4-fluorop...
Compound Q&A

What are the physical and chemical properties of 4,5,6,7-Tetrahydro-1H-indazole hydrochloride (CAS: 18161-11-0)?

4,5,6,7-Tetrahydro-1H-indazole hydrochloride is a white crystalline solid with a...

18161-11-04,5,6,7-Tetrahydro-1...
Compound Q&A

What is (2R)-1-Methoxy-3-phenyl-2-propanamine (CAS: 59919-07-2)?

(2R)-1-Methoxy-3-phenyl-2-propanamine is a chiral organic compound with the CAS ...

59919-07-2(2R)-1-Methoxy-3-phe...
Compound Q&A

What industries use Ethyl 1-(1-phenylethyl)-1H-imidazole-5-carboxylate (CAS: 56649-47-9)?

Ethyl 1-(1-phenylethyl)-1H-imidazole-5-carboxylate is used in various industries...

56649-47-9Ethyl 1-(1-phenyleth...
Compound Q&A

What regulatory guidelines apply to 4-[(1E,3S)-1-(4-Hydroxyphenyl)-1,4-pentadien-3-yl]phenol (CAS: 17676-24-3)?

4-[(1E,3S)-1-(4-Hydroxyphenyl)-1,4-pentadien-3-yl]phenol (CAS: 17676-24-3) falls...

17676-24-34-[(1E,3S)-1-(4-Hydr...
Compound Q&A

What industries use (S)-3-Amino-5-phenylpentanoic acid hydrochloride (CAS: 331846-97-0)?

(S)-3-Amino-5-phenylpentanoic acid hydrochloride is primarily used in the pharma...

331846-97-0(S)-3-Amino-5-phenyl...
Compound Q&A

How is 7-methoxy-1-benzothiophene-2-carboxylic acid (CAS: 88791-07-5) typically synthesized?

7-Methoxy-1-benzothiophene-2-carboxylic acid is typically synthesized by reactin...

88791-07-57-methoxy-1-benzothi...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.