Electrical conductivity of reverse micelles in supercritical carbon dioxide
Literature Information
Christian Blattner, Jürgen Bittner, Georg Schmeer, Werner Kunz
The conductivity of water/ClPFPE-NH4/scCO2 systems is studied over a wide range of pressures and droplet volume fractions at 35 °C and at two constant water-to-surfactant molar ratios, W0 = 10.3 and 18.7, respectively. The results are interpreted according to three different models for low, intermediate and high concentrations of water and surfactant. Information is obtained about a possible bulk-like behaviour of water, about the approximate size of the micelles, about micellar percolation, and about changes of CO2–water droplet interactions with pressure.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











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