Phase behaviour of a two-dimensional Lennard-Jones binary mixture Part II. Type III to Type I transition

Literature Information

Publication Date 2002-02-12
DOI 10.1039/B107990P
Impact Factor 3.676
Authors

Osvaldo H. Scalise, Moises Silbert


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Abstract

Calculations are presented on the phase behaviour of quasi-two-dimensional Lennard-Jones fluid binary mixtures. The results obtained show a Type III phase equilibria diagram similar to that observed in three-dimensional binary mixtures. A transition is found from a Type III to a Type I phase equilibria diagram. The study uses a mean field theory similar to that applied to a binary mixture of hard spheres with immersed point dipoles that showed that the transition was from Type III to Type IV instead. Consequently we suggest that, within mean field theories, a Type IV phase diagram is only obtained if the interactions are angle-dependent.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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