Novel phase-transition behavior near liquid/liquid critical points of aqueous solutions: Formation of a third phase at the interface
Literature Information
J. Jacob, M. A. Anisimov, J. V. Sengers, A. Oleinikova, H. Weingärtner, A. Kumar
We report a novel phase behavior in aqueous solutions of simple organic solutes near their liquid/liquid critical points, where a solid-like third phase appears at the liquid/liquid interface. The phenomenon has been found in three different laboratories. It appears in many aqueous systems of organic solutes and becomes enhanced upon the addition of salt to these solutions.
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