Detection of muoniated organic free radicals in supercritical water
Literature Information
Paul W. Percival, Khashayar Ghandi, Jean-Claude Brodovitch, Brenda Addison-Jones, Iain McKenzie
Muoniated free radicals have been detected in muon-irradiated aqueous solutions at high temperatures and pressures. Results are presented for the cyclohexadienyl radical, formed by muonium addition to benzene, and for tert-butyl, formed by reaction of muonium with isobutene, itself formed in situ from the dehydration of the starting material, tert-butanol. This is the first report of the direct identification of organic free radicals in near critical and supercritical water.
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