Electrolyte composition and ionic mobility in micropores
Literature Information
Bertel Kastening, Matthias Heins
The electrolyte in the micropores of activated carbon, in contact with aqueous 0.3 M potassium fluoride solution and at zero charge potential, consists essentially of ion pairs along with merely 0.06 M free ions. The mobilities are 5 and 1.4 S cm2 mol−1 for K+ and F−, respectively. Exchange of ions with the external electrolyte, upon stepwise change of the electrode potential, was assisted by macropores.
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Physical Chemistry Chemical Physics

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