Electrolyte composition and ionic mobility in micropores

Literature Information

Publication Date 2000-10-27
DOI 10.1039/B005206J
Impact Factor 3.676
Authors

Bertel Kastening, Matthias Heins


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Abstract

The electrolyte in the micropores of activated carbon, in contact with aqueous 0.3 M potassium fluoride solution and at zero charge potential, consists essentially of ion pairs along with merely 0.06 M free ions. The mobilities are 5 and 1.4 S cm2 mol−1 for K+ and F−, respectively. Exchange of ions with the external electrolyte, upon stepwise change of the electrode potential, was assisted by macropores.

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Front cover

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DOI: 10.1039/B715298C

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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