A novel approach towards synthesis of benzothiazoles and benzimidazoles: Eosin Y-catalyzed photo-triggered C–S and C–N bond formation

Literature Information

Publication Date 2023-11-15
DOI 10.1039/D3NJ04374F
Impact Factor 3.591
Authors

Khushbu Rajput, Vishal Singh, Arsala Kamal, Himanshu Kumar Singh, Sundaram Singh, Vandana Srivastava


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Abstract

A novel metal-free and environment-friendly approach for synthesizing biologically important moieties, benzothiazoles and benzimidazoles, under visible light irradiation using photocatalyst Eosin Y, ethanol:water as a green solvent and atmospheric air as an oxidant has been developed. Using an organic dye, Eosin Y, provided a mild and economical catalytic system to synthesize a series of benzothiazoles and benzimidazoles in good to excellent yields. Besides, the photocatalytic system does not require an additional oxidant, which is good for the environment. This method has several advantages, including the absence of metals, low cost, environmental friendliness, green solvent, non-toxicity, ease of handling, and renewable energy sources such as visible light.

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New Journal of Chemistry

New Journal of Chemistry
CiteScore: 5.3
Self-citation Rate: 3.7%
Articles per Year: 2153

NJC (New Journal of Chemistry) is a broad-based primary journal encompassing all branches of chemistry and its sub-disciplines. It contains full research articles, communications, perspectives and focus articles. This well-established journal, owned by the Centre National de la Recherche Scientifique (CNRS) of France, has been co-published with the Royal Society of Chemistry since January 1998. NJC is the forum for the publication of high-quality, original and significant work that opens new directions in chemistry or other scientific disciplines. In addition to having a significant chemical component, work published in NJC must demonstrate that it will have an impact on areas of research other than that of the reported work.

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