The synthesis and topochemical polymerization of o-carborane-based diacetylene macrocycles

Literature Information

Publication Date 2023-10-12
DOI 10.1039/D3NJ03491G
Impact Factor 3.591
Authors

Meigui Fu, Shuai Yuan, Qi Qu, Yaofeng Yuan, Caixia Lin


View Original

Abstract

A kind of o-carborane-based macrocycle was synthesized via oxidative coupling of acetylene-terminated o-carborane precursors. Single crystal X-ray diffraction analysis unambiguously revealed their unique porous supramolecular structures, which displayed micropore characteristics. Interestingly, the crystal structure of macrocyclic CBMC-2 formed through non-covalent interactions shows packing parameters corresponding to the ideal polymerization parameters. UV-vis, DSC and X-ray analyses indicated that the crystals of macrocycle CBMC-2 could undergo diacetylene topochemical polymerization inside the solid by heating. This was confirmed using Raman spectroscopy and solid-state 13C NMR spectroscopy. This work provides a method for synthesizing carborane supramolecular polymers.

Related Literature

Rapid and improved characterization of therapeutic antibodies and antibody related products using IdeS digestion and subunit analysis

Jonathan Sjögren, Fredrik Olsson, Alain Beck

2016-05-04 Minireview

DOI: 10.1039/C6AN00071A

Green synthesis of up- and down-conversion photoluminescent carbon dots from coffee beans for Fe3+ detection and cell imaging

Wanyu Zhang, Lihua Jia, Rui Yang, Yu Zhang, Zhenlong Zhao

2019-10-28 Paper

DOI: 10.1039/C9AN01953G

A novel logic gate based on liquid-crystals responding to the DNA conformational transition

Fubing Xiao, Hui Tan, Yan Wu, Shuzhen Liao, Zhaoyang Wu, Guoli Shen, Ruqin Yu

2016-04-13 Communication

DOI: 10.1039/C6AN00504G

Functionalization of metal nanoclusters for biomedical applications

Nirmal Goswami, Huang-Hao Yang, Jianping Xie

2016-04-21 Critical Review

DOI: 10.1039/C6AN00773B

Competitive adsorption on gold nanoparticles for human papillomavirus 16 L1 protein detection by LDI-MS

Jing Han, Zhihua Wang, Lihui Yin, Wei Zhang, You Peng, Zongxiu Nie

2019-09-29 Paper

DOI: 10.1039/C9AN01612K

Surface-enhanced Raman spectroscopy (SERS) characterisation of abasic sites in DNA duplexes

Luca Guerrini

2019-11-05 Communication

DOI: 10.1039/C9AN02040C

You might also like

Compound Q&A

What precautions should be taken when handling 4-(2-Furylmethyl)thiomorpholine 1,1-dioxide (CAS: 79206-94-3)?

When handling 4-(2-Furylmethyl)thiomorpholine 1,1-dioxide (CAS: 79206-94-3), it ...

79206-94-34-(2-Furylmethyl)thi...
Compound Q&A

What precautions should be taken when handling 4-Chloro-N-[2-(4-morpholinyl)ethyl]benzamide (CAS: 71320-77-9)?

When handling 4-Chloro-N-[2-(4-morpholinyl)ethyl]benzamide (CAS: 71320-77-9), it...

71320-77-94-Chloro-N-[2-(4-mor...
Compound Q&A

How should waste containing 2-[2-(2-Methoxyethoxy)ethoxy]ethyl 4-methylbenzenesulfonate (CAS: 62921-74-8) be handled?

Waste containing this compound (CAS: 62921-74-8) should be handled according to ...

62921-74-82-[2-(2-Methoxyethox...
Compound Q&A

How should waste containing (S)-Methyl 2-amino-3-cyclohexylpropanoate be handled?

Waste containing (S)-Methyl 2-amino-3-cyclohexylpropanoate should be collected i...

40056-18-6(S)-Methyl 2-amino-3...
166882-70-85-({4-[(2S,4R)-4-Hyd...
Compound Q&A

Are there alternatives to (2E)-3-(3,4-Dichlorophenyl)acrylic acid (CAS: 7312-27-8) in synthesis?

There are several alternatives to (2E)-3-(3,4-Dichlorophenyl)acrylic acid in syn...

7312-27-8(2E)-3-(3,4-Dichloro...
Compound Q&A

How should Ethyl 6-(2-nitrophenyl)imidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 925437-84-9) be stored?

Ethyl 6-(2-nitrophenyl)imidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 925437-84...

925437-84-9Ethyl 6-(2-nitrophen...
Compound Q&A

How should waste containing 2-(1,3-Thiazol-2-yl)ethanamine (CAS: 18453-07-1) be handled?

Waste containing 2-(1,3-Thiazol-2-yl)ethanamine (CAS: 18453-07-1) should be coll...

18453-07-12-(1,3-Thiazol-2-yl)...
Compound Q&A

How is Methyl 5-iodo-2-methylbenzoate (CAS: 103440-54-6) typically synthesized?

Methyl 5-iodo-2-methylbenzoate can be synthesized through the iodination of meth...

103440-54-6Methyl 5-iodo-2-meth...
Compound Q&A

How is 5-Chloro[1,2,4]triazolo[1,5-a]pyridine (CAS: 1427399-34-5) typically synthesized?

5-Chloro[1,2,4]triazolo[1,5-a]pyridine is commonly synthesized via the condensat...

1427399-34-55-Chloro[1,2,4]triaz...

Source Journal

New Journal of Chemistry

New Journal of Chemistry
CiteScore: 5.3
Self-citation Rate: 3.7%
Articles per Year: 2153

NJC (New Journal of Chemistry) is a broad-based primary journal encompassing all branches of chemistry and its sub-disciplines. It contains full research articles, communications, perspectives and focus articles. This well-established journal, owned by the Centre National de la Recherche Scientifique (CNRS) of France, has been co-published with the Royal Society of Chemistry since January 1998. NJC is the forum for the publication of high-quality, original and significant work that opens new directions in chemistry or other scientific disciplines. In addition to having a significant chemical component, work published in NJC must demonstrate that it will have an impact on areas of research other than that of the reported work.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.