Coincident measurement of photo-ion circular dichroism and photo-electron circular dichroism in 1-phenylethylamine
Literature Information
Carl Stefan Lehmann, Demian Botros, Karl-Michael Weitzel
Here, we report the coincident measurement of PICD and PECD effects in 1-phenylethylamine upon multiphoton ionization. Both photo-ion circular dichroism (PICD) and photo-electron circular dichroism (PECD) are methods to distinguish enantiomers. In PICD, a difference in total ion yields upon multiphoton ionization with circular polarized light is measured, whereas, in PECD, circular dichroism is observed in the angular distribution of the photoelectrons. Here, we report on our continuous effort to measure the PICD and PECD effects in coincidence, i.e. simultaneously under the same measurement conditions using a home-built photoion–photoelectron coincidence spectrometer. Pure samples of R-(+)-1-phenylethylamine and S-(−)-1-phenylethylamine have been photo-ionized using a femtosecond laser operated at 394 nm.
Related Literature
Nanogravimetric observation of unexpected ion exchange characteristics for polypyrrole film p-doping in a deep eutectic ionic liquid
Magdalena A. Skopek, Mohamoud A. Mohamoud, Karl S. Ryder, A. Robert Hillman
DOI: 10.1039/B819084D
α-Zirconium phosphonates: versatile supports for N-heterocyclic carbenes
Simona Chessa, Nigel J. Clayden, Manfred Bochmann, Joseph A. Wright
DOI: 10.1039/B821301A
Photocatalytic printing of inorganic nanopatterns via poly(styrene-block-carbosilane) copolymer thin films on titania substrates
Juan Peng, Alejandra Garcia Marcos, Seong-Jun Jeong, Holger Frey, Dong Ha Kim
DOI: 10.1039/B816398G
Morphology effect on antibacterial activity of cuprous oxide
Huan Pang, Feng Gao, Qingyi Lu
DOI: 10.1039/B816670F
One-pot noncovalent method to functionalize multi-walled carbon nanotubes using cyclomatrix-type polyphosphazenes
Jianwei Fu, Xiaobin Huang, Yawen Huang, Jiawei Zhang, Xiaozhen Tang
DOI: 10.1039/B818071G
Exceptionally high H2storage by a metal–organic polyhedral framework
Yong Yan, Xiang Lin, Sihai Yang, Alexander J. Blake, Anne Dailly, Neil R. Champness, Peter Hubberstey, Martin Schröder
DOI: 10.1039/B900013E
Chemistry and structural determination of botcinolides, botcinins, and botcinic acids
Isamu Shiina, Hiroki Fukui
DOI: 10.1039/B814375G
Model systems for flavoenzyme activity: an investigation of the role functionality attached to the C(7) position of the flavin unit has on redox and molecular recognition properties‡
Stuart T. Caldwell, Louis J. Farrugia, Shanika Gunatilaka Hewage, Nadiya Kryvokhyzha, Vincent M. Rotello, Graeme Cooke
DOI: 10.1039/B900269N
Stabilizing single-molecular Raman spectrum of a nonbonding molecule on Ag nanoparticles
Zhixun Luo, Yi Luo, Jie Li, Kai Liu, Hongbing Fu, Ying Ma, Jiannian Yao
DOI: 10.1039/B819402E
You might also like
What precautions should be taken when handling 2-Methyl-2-propanyl 5-amino-2-thiophenecarboxylate (CAS: 1498311-57-1)?
When handling 2-Methyl-2-propanyl 5-amino-2-thiophenecarboxylate (CAS: 1498311-5...
What are the physical and chemical properties of 5-Bromo-1,2-dichloro-3-fluorobenzene (CAS: 1000572-93-9)?
5-Bromo-1,2-dichloro-3-fluorobenzene (CAS: 1000572-93-9) is a crystalline solid ...
How should (2R)-2-Amino-2-(4-bromophenyl)ethanol (CAS: 354153-64-3) be stored?
(2R)-2-Amino-2-(4-bromophenyl)ethanol (CAS: 354153-64-3) should be stored in a c...
What regulatory guidelines apply to Methyl 4-(aminomethyl)tetrahydro-2H-pyran-4-carboxylate hydrochloride (CAS: 362707-24-2)?
Methyl 4-(aminomethyl)tetrahydro-2H-pyran-4-carboxylate hydrochloride (CAS: 3627...
What are the main uses of 1,4-dimethyl-1H-pyrazole-5-sulfonyl chloride (CAS: 1174834-52-6)?
1,4-Dimethyl-1H-pyrazole-5-sulfonyl chloride is primarily used as an intermediat...
Is Dinaphtho[1,2-b:2',1'-d]furan (CAS: 239-69-0) safe?
Dinaphtho[1,2-b:2',1'-d]furan is generally safe when handled with appropriate pe...
What is the market or research trend for 7-Methyl-7,9-dihydro-1H-purine-2,6,8(3H)-trione (CAS: 612-37-3)?
The market for 7-Methyl-7,9-dihydro-1H-purine-2,6,8(3H)-trione (CAS: 612-37-3) i...
What are the physical and chemical properties of 2-(4-Chlorophenyl)malonaldehyde (CAS: 205676-17-1)?
2-(4-Chlorophenyl)malonaldehyde (CAS: 205676-17-1) is a colorless or light yello...
How is 2-Methylchrysene (CAS: 3351-32-4) typically synthesized?
2-Methylchrysene (CAS: 3351-32-4) is typically synthesized via the reaction of c...
Is N-(6-aminopyrimidin-4-yl)acetamide (CAS: 89533-23-3) safe?
N-(6-aminopyrimidin-4-yl)acetamide (CAS: 89533-23-3) is generally considered saf...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











![1-Oxa-8-azaspiro[4.5]decan-3-ol structure 1-Oxa-8-azaspiro[4.5]decan-3-ol structure](https://static.chemtradehub.com/structs/757/757239-76-2-a0ec.webp)


