amine structure](https://static.chemtradehub.com/structs/629/62924-61-2-0728.webp "[(2-chlorophenyl)methyl](ethyl)amine structure")
One-step hydrogenolysis of 5-hydroxymethylfurfural to 1,2,6-hexanetriol using a Pt@MIL-53-derived Pt@Al2O3 catalyst and NaBH4 in aqueous media
Literature Information
Publication Date
2021-07-03
DOI
10.1039/D1SE00802A
Impact Factor
6.367
Authors
Babasaheb M. Matsagar, Hsiang-L. Sung, Jyun-Yi Yeh, Ching-Tien Chen
View Original
Abstract
Herein hydrogenolysis of biomass-derived 5-hydroxymethylfurfural (HMF) into 1,2,6-hexanetriol (1,2,6-HT) has been demonstrated using a MOF-derived Pt@Al2O3 catalyst and NaBH4 as the hydrogen source. The result showed a 63% 1,2,6-HT yield under relatively mild reaction conditions in aqueous media. The in situ method used for catalyst synthesis improved the homogeneous distribution of Pt species on the Al2O3 support. The reaction pathway for the hydrogenolysis of HMF-to-1,2,6-HT conversion exhibited the formation of 2,5-bis(hydroxymethyl)-furan (2,5-DHF) and 2,5-bis(hydroxymethyl)tetrahydrofuran (THFDM) intermediates. The kinetic study revealed that the activation energy of THFDM (78.7 kJ mol−1) is higher than that of 1,2,6-HT (64.7 kJ mol−1), indicating that lower reaction temperature favors the production of 1,2,6-HT.
Recommended Journals
Related Literature
Hyperbranched polymer hydrogels with large stimuli-responsive changes in storage moduli and peroxide-induced healing
Prathyusha Chimala, M. Mario Perera, Aissatou Wade, Tucker McKenzie, Joshua Allor, Neil Ayres
2021-07-15
Paper
DOI: 10.1039/D1PY00560J
Solvent-induced frequency shifts in the infrared spectrum of acetone in organic solvents
Paper
DOI: 10.1039/A905776E
Nanosecond time resolved emission spectroscopy of aminocoumarins in AOT reversed micelles
Paper
DOI: 10.1039/A906191F
Sulfur uptake and exchange, HDS activity and structure of sulfided, Al2O3 supported MoOx, PdMoOx and PtMoOx catalysts
Zoltán Paál, Tamás Koltai, (the late) Károly Matusek, Jean-Marie Manoli, Claude Potvin, Martin Muhler, Ute Wild, Pál Tétényi
2001-03-19
Paper
DOI: 10.1039/B009047F
Positrons in doped pyrene
Tomasz Goworek, Czesław Rybka, Jan Wawryszczuk
2001-03-29
Paper
DOI: 10.1039/B008826I
Redox behaviour of SnO2 nanoparticles encapsulated in the pores of zeolites towards reductive gas atmospheres studied by in situ diffuse reflectance UV/Vis and Mössbauer spectroscopy
Meike Warnken, Karoly Lázár, Michael Wark
2001-04-10
Paper
DOI: 10.1039/B009045J
An amorphous approach to the structure of a Pt–Fe/γ-Al2O3catalyst characterized by XAFS
Li-wu Lin, Yuan Kou, Ming Zou, Zhen Yan
2001-03-29
Paper
DOI: 10.1039/B100690H
You might also like
Compound Q&A
What are the main uses of (3.beta.)-3-Hydroxy-N,N-dimethyl-chol-5-en-24-amide (CAS: 79066-03-8)?
(3.beta.)-3-Hydroxy-N,N-dimethyl-chol-5-en-24-amide (CAS: 79066-03-8) is primari...
79066-03-8(3.beta.)-3-Hydroxy-...
Compound Q&A
What regulatory guidelines apply to 5-(aminomethyl)-2-methoxyphenol (CAS: 89702-89-6)?
5-(Aminomethyl)-2-methoxyphenol (CAS: 89702-89-6) is classified under GHS as a s...
89702-89-65-(aminomethyl)-2-me...
Compound Q&A
What is Thieno[2,3-c]pyridin-7(6H)-one (CAS: 28981-13-7)?
Thieno[2,3-c]pyridin-7(6H)-one (CAS: 28981-13-7) is a heterocyclic organic compo...
28981-13-7Thieno[2,3-c]pyridin...
Compound Q&A
Is 1-[(6-Methoxy-3-pyridinyl)methyl]-4-piperidinamine dihydrochloride (CAS: 1185311-28-7) safe?
1-[(6-Methoxy-3-pyridinyl)methyl]-4-piperidinamine dihydrochloride is generally ...
1185311-28-71-[(6-Methoxy-3-pyri...
Compound Q&A
What regulatory guidelines apply to [(2E)-3-Phenyl-2-propen-1-yl]phosphonic acid (CAS: 146404-58-2)?
[(2E)-3-Phenyl-2-propen-1-yl]phosphonic acid (CAS: 146404-58-2) is regulated und...
146404-58-2[(2E)-3-Phenyl-2-pro...
Compound Q&A
What regulatory guidelines apply to 6-Bromo-7-methoxyquinoline (CAS: 1620515-86-7)?
6-Bromo-7-methoxyquinoline (CAS: 1620515-86-7) falls under the scope of the Glob...
1620515-86-76-Bromo-7-methoxyqui...
Compound Q&A
What industries use (2R)-1-(1-Benzofuran-2-yl)-N-propyl-2-pentanamine (CAS: 260550-89-8)?
This compound is primarily used in the pharmaceutical industry for the developme...
260550-89-8(2R)-1-(1-Benzofuran...
Compound Q&A
What are the main uses of 1-Ethyl-7-[2-methyl-6-(4H-1,2,4-triazol-3-yl)-3-pyridinyl]-3,5-dihydropyrazino[2,3-b]pyrazin-2(1H)-one (CAS: 1228013-15-7)?
1-Ethyl-7-[2-methyl-6-(4H-1,2,4-triazol-3-yl)-3-pyridinyl]-3,5-dihydropyrazino[2...
1228013-15-71-Ethyl-7-[2-methyl-...
Compound Q&A
Are there alternatives to {5-(Acryloylamino)-2-[(dimethylamino)methyl]phenyl}boronic acid (CAS: 1217500-78-1) in synthesis?
Alternative reagents such as 2-[(dimethylamino)methyl]phenylboronic acid or rela...
1217500-78-1{5-(Acryloylamino)-2...
Compound Q&A
What is 3-(Piperidin-4-yloxy)pyridine (CAS: 310881-48-2)?
3-(Piperidin-4-yloxy)pyridine (CAS: 310881-48-2) is an organic compound with the...
310881-48-23-(Piperidin-4-yloxy...
Source Journal
Recommended Compounds
![7-Bromo-5-chloro-1H-pyrazolo[4,3-b]pyridine structure](https://static.chemtradehub.com/structs/135/1351813-70-1-a716.webp "7-Bromo-5-chloro-1H-pyrazolo[4,3-b]pyridine structure")
2-Amino-2-(4-(pyridin-2-YL)phenyl)acetic acid hydrochloride
CAS Number:
1135818-89-1
Molecular Formula:
C13H13ClN2O2
methyl 6-bromo-3-formyl-1H-indole-4-carboxylate
CAS Number:
1353636-63-1
Molecular Formula:
C11H8BrNO3
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.