(3beta,7beta,12beta)-3,7,12-Trihydroxy-11,15,23-trioxolanost-8-en-26-oic acid
CAS Number:
98665-22-6
Molecular Formula:
C30H44O8
Friedel–Crafts acylation of antiaromatic norcorroles: electronic and steric modulation of the paratropic current
Literature Information
Publication Date
2021-06-07
DOI
10.1039/D1QO00621E
Impact Factor
5.281
Authors
Sha Li, Oskar Smaga, Yahan Sun, Xiaofang Li, Marzena Sukniewicz, Piotr J. Chmielewski
View Original
Abstract
Acyl chlorides react with norcorrolatonickel(II) in dichloromethane in the presence of AlCl3 at room temperature affording two isomeric monoketone derivatives in moderate yields. For acetyl chloride, also diketones were detected and separated. Spectroscopic and electrochemical characterization studies were corroborated using DFT calculations.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
3-(3-Ethyl-1-methyl-3-azepanyl)phenol hydrochloride (1:1)
CAS Number:
59263-76-2
Molecular Formula:
C15H24ClNO
![1,2-Diphenyl-4-[2-(phenylsulfinyl)ethyl]-3,5-pyrazolidinedione structure](https://static.chemtradehub.com/structs/57-/57-96-5-efcc.webp "1,2-Diphenyl-4-[2-(phenylsulfinyl)ethyl]-3,5-pyrazolidinedione structure")
1,2-Diphenyl-4-[2-(phenylsulfinyl)ethyl]-3,5-pyrazolidinedione
CAS Number:
57-96-5
Molecular Formula:
C23H20N2O3S
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