Cobalt- and iron-catalyzed regiodivergent alkene hydrosilylations

Literature Information

Publication Date 2021-02-25
DOI 10.1039/D1QO00018G
Impact Factor 5.281
Authors

Sheng Zhang, Jia-Shia Liao, Daniel K. Unruh, Guigen Li, Michael Findlater


View Original

Abstract

A complementary set of base metal catalysts has been developed for regiodivergent alkene hydrosilylations: iron complexes of amine-iminopyridine ligands are selective for Markovnikov hydrosilylations (branched/linear up to >99 : 1), while the cobalt complexes bearing the same type of ligands provide excellent levels of anti-Markovnikov selectivity (linear/branched up to >99 : 1). Both systems exhibit high efficiency and wide functional group tolerance.

Related Literature

Stereochemistry of hydrogen removal from the ‘unactivated’ C-3 position of 4-hydroxybutyryl-CoA catalysed by 4-hydroxybutyryl-CoA dehydratase

Richard Scott, Ulrike Näser, Peter Friedrich, Thorsten Selmer, Wolfgang Buckel, Bernard T. Golding

2004-04-23 Communication

DOI: 10.1039/B402322F

NH4[BPO4F]: A novel open-framework ammonium fluorinated borophosphate with a zeolite-like structure related to gismondine topology

Man-Rong Li, Wei Liu, Ming-Hui Ge, Hao-Hong Chen, Xin-Xin Yang, Jing-Tai Zhao

2004-04-29 Communication

DOI: 10.1039/B402966F

Efficient synthesis of a nucleoside-diphospho-exo-glycal displaying time-dependent inactivation of UDP-galactopyranose mutase

Audrey Caravano, Stéphane P. Vincent, Pierre Sinaÿ

2004-04-23 Communication

DOI: 10.1039/B402469A

Bond energy, aromatic stabilization energy and strain in IPR fullerenes

Michał K. Cyrański, Siân T. Howard, Michał L. Chodkiewicz

2004-09-21 Communication

DOI: 10.1039/B408903K

Self-assembly of aluminium–salen coupled nanostructures from encoded modules with cleavable disulfide DNA-linkers

Raymond S. Brown, Morten Nielsen, Kurt V. Gothelf

2004-05-27 Communication

DOI: 10.1039/B403956D

Ring-closing metathesis in biphasic BMI·PF6ionic liquid/toluene medium: a powerful recyclable and environmentally friendly process

Hervé Clavier, Nicolas Audic, Marc Mauduit, Jean-Claude Guillemin

2004-08-25 Communication

DOI: 10.1039/B407964G

Oxy-peptide nucleic acid with a pyrrolidine ring that is configurationally optimized for hybridization with DNA

Mizuki Kitamatsu, Masanori Shigeyasu, Tomoyuki Okada, Masahiko Sisido

2004-04-23 Communication

DOI: 10.1039/B401057D

Azobenzene derivatives with a long alkyl chain and aminoxyls

Masahiro Fujino, Takamitsu Amano, Hiroki Akutsu, Jun-ichi Yamada, Shin'ichi Nakatsuji

2004-09-03 Communication

DOI: 10.1039/B408432B

Stereospecific peptide folds. A rationally designed molecular bracelet

Soumendra Rana, Bijoy Kundu, Susheel Durani

2004-09-20 Communication

DOI: 10.1039/B410532J

Shuttling through reversible covalent chemistry

David A. Leigh, Emilio M. Pérez

2004-09-23 Communication

DOI: 10.1039/B412570C

You might also like

Compound Q&A

What precautions should be taken when handling 2-Chloro-1,2-bis(4-methylphenyl)ethanone (CAS: 71193-32-3)?

When handling 2-Chloro-1,2-bis(4-methylphenyl)ethanone (CAS: 71193-32-3), it is ...

71193-32-32-Chloro-1,2-bis(4-m...
Compound Q&A

What industries use 4-Ethoxy-3-(5-methyl-4-oxo-7-propyl-1,4-dihydroimidazo[5,1-f][1,2,4]triazin-2-yl)benzenesulfonyl chloride (CAS: 224789-26-8)?

4-Ethoxy-3-(5-methyl-4-oxo-7-propyl-1,4-dihydroimidazo[5,1-f][1,2,4]triazin-2-yl...

224789-26-84-Ethoxy-3-(5-methyl...
Compound Q&A

How should Methyl 3-Oxo-4-Androsten-17-Carboxylate (CAS: 2681-55-2) be stored?

Methyl 3-Oxo-4-Androsten-17-Carboxylate (CAS: 2681-55-2) should be stored in a c...

2681-55-2Methyl 3-Oxo-4-Andro...
Compound Q&A

What are the main uses of (R)-3-Amino-4-(3-hexylphenylamino)-4-oxobutylphosphonic acid (CAS: 909725-61-7)?

(R)-3-Amino-4-(3-hexylphenylamino)-4-oxobutylphosphonic acid is primarily used i...

909725-61-7(R)-3-Amino-4-(3-hex...
Compound Q&A

What regulatory guidelines apply to 2-Methyl-2-propanyl 3-amino-3-carbamoyl-1-azetidinecarboxylate (CAS: 1254120-14-3)?

2-Methyl-2-propanyl 3-amino-3-carbamoyl-1-azetidinecarboxylate (CAS: 1254120-14-...

1254120-14-32-Methyl-2-propanyl ...
Compound Q&A

Are there alternatives to (E)-4-(tert-Butoxy)-4-oxobut-2-enoic acid (CAS: 135355-96-3) in synthesis?

There are alternative reagents that can be used in synthesis instead of (E)-4-(t...

135355-96-3(E)-4-(tert-Butoxy)-...
Compound Q&A

What are the physical and chemical properties of [2-(3-Chlorophenyl)-1,3-thiazol-4-yl]methanol (CAS: 121202-20-8)?

[2-(3-Chlorophenyl)-1,3-thiazol-4-yl]methanol (CAS: 121202-20-8) is a crystallin...

121202-20-8[2-(3-Chlorophenyl)-...
166249-17-8Methyl (2S)-[(4S)-2,...
Compound Q&A

What is the market or research trend for 1-Bromo-2-isocyanatoethane (CAS: 42865-19-0)?

The market for 1-Bromo-2-isocyanatoethane (CAS: 42865-19-0) is driven by its use...

42865-19-01-Bromo-2-isocyanato...
Compound Q&A

What are the main uses of 4-Nitro-D-phenylalanine hydrochloride (CAS: 147065-06-3)?

4-Nitro-D-phenylalanine hydrochloride (CAS: 147065-06-3) is primarily used in re...

147065-06-34-Nitro-D-phenylalan...

Source Journal

Organic Chemistry Frontiers

Organic Chemistry Frontiers
CiteScore: 7.8
Self-citation Rate: 8.7%
Articles per Year: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.