Effect of nitrogen substitution on luminescence tuning in garnets

Literature Information

Publication Date 2020-04-02
DOI 10.1039/D0CP00586J
Impact Factor 3.676
Authors

Zhen Song, Quanlin Liu


View Original

Abstract

Anionic substitution is attracting research interest as a property modulation strategy. Although the effect of nitrogen incorporation on luminescence tuning has been widely reported, the correlation between dodecahedral expansion on Si4+–N3− co-substitution and crystal-field splitting of Ce3+ in garnets is rarely discussed. This work is devoted to unraveling the structure–property relationship between anionic substitution and spectroscopy tuning. Ligand movement patterns of a dodecahedron and an octahedron are investigated for tetragonal distortion and inter-facial distance, both of which indicate an energy level shift originating from the crystal-field effect. The quantitative crystal-field calculation is performed on the basis of ligand coordinates to derive the analytical expression for further confirmation. This work complements the substitution effects of both cationic and anionic chemical species on spectral tuning in garnets, and will be helpful in material design and property modulation of garnet-based luminescent materials.

Related Literature

Back cover

2023-12-13 Cover

DOI: 10.1039/D3NP90055J

Removal of total chromium in wastewater via simultaneous photocatalysis and adsorption using calcium silicate hydrate-based composites

Min Liu, Qi Liu, Xue-Ting Jin, Ya-Chen Zou, Di-Ning Li, Pan Feng, Yang-Hui Luo

2023-10-19 Paper

DOI: 10.1039/D3TA05384A

Composite membranes based on polyvinyl alcohol and lamellar solids for water decontamination

Maria Bastianini, Michele Sisani, Annarita Petracci, Irene Di Guida, Riccardo Narducci

2023-12-21 Paper

DOI: 10.1039/D3NJ04942F

Back cover

2024-01-24 Cover

DOI: 10.1039/D4NP90004A

Correction: Hot off the Press

2024-01-03 Correction

DOI: 10.1039/D3NP90056H

One-pot construction of highly functionalized 4H-chromenes using K-10 montmorillonite in aqueous medium

Mohd Yeshab Ansari, Sumedha Swarnkar

2023-12-02 Paper

DOI: 10.1039/D3NJ04619B

Multifunctional underwater superoleophobic cellulose-based composite aerogel with oil/water separation, dye adsorption, and antibacterial activities

Zhen Zhang, Linyan Zhao, Lin Cui, DongMei Li, Xing Tian, Zhiyong Liu, Shenglin Liu

2023-12-15 Paper

DOI: 10.1039/D3NJ05042D

Eco-efficient pickering foams: leveraging sugarcane waste-derived cellulose nanofibres

Nasim Amiralian, Sandya S. A. Athukoralalage

2023-11-03 Paper

DOI: 10.1039/D3TA04917E

An integrated-milliampere-level hydroelectric generator utilizing chemical-doped P-type and N-type graphites

Dunren He, Wanyi Nie, Huihui Huang

2023-10-24 Paper

DOI: 10.1039/D3TA06080B

Facile one-pot synthesis of a waste copper phthalocyanine-derived nanocomposite for efficiently removing dyes from wastewater

Munazza Munshi, Tanzila Khan, Madhuri Bhakare, Ankita Kadam, Surajit Some

2024-01-09 Paper

DOI: 10.1039/D3NJ05351B

You might also like

Compound Q&A

How should waste containing N-Methoxy-N-methyl-1,3-thiazole-5-carboxamide (CAS: 898825-89-3) be handled?

Waste containing N-Methoxy-N-methyl-1,3-thiazole-5-carboxamide (CAS: 898825-89-3...

898825-89-3N-Methoxy-N-methyl-1...
Compound Q&A

How should N-(4-Biphenylyl)dibenzo[b,d]furan-4-amine (CAS: 1318338-47-4) be stored?

N-(4-Biphenylyl)dibenzo[b,d]furan-4-amine should be stored in a tightly sealed c...

1318338-47-4N-(4-Biphenylyl)dibe...
Compound Q&A

What is the market or research trend for 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid (CAS: 1713-07-1)?

The market for 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid (CAS: 1713-07-1) is...

1713-07-13-Acetamido-5-amino-...
Compound Q&A

How should Benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-galactopyranoside (CAS: 61820-03-9) be stored?

Benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-galactopyranoside (CAS: 61820-03-9) ...

61820-03-9Benzyl 2-O-acetyl-3,...
Compound Q&A

What regulatory guidelines apply to 2-Ethylpiperazine dihydrochloride (CAS: 438050-52-3)?

2-Ethylpiperazine dihydrochloride (CAS: 438050-52-3) is regulated under the Glob...

438050-52-32-Ethylpiperazine di...
Compound Q&A

What regulatory guidelines apply to 1,1'-[1,3-Phenylenebis(methylene)]bis(3-methyl-1H-pyrrole-2,5-dione) (CAS: 119462-56-5)?

1,1'-[1,3-Phenylenebis(methylene)]bis(3-methyl-1H-pyrrole-2,5-dione) (CAS: 11946...

119462-56-51,1'-[1,3-Phenyleneb...
Compound Q&A

Are there alternatives to 5-Fluoro-2-(1-pyrrolidinyl)pyridine (CAS: 1287217-79-1) in synthesis?

Several alternatives can be used in the synthesis of 5-Fluoro-2-(1-pyrrolidinyl)...

1287217-79-15-Fluoro-2-(1-pyrrol...
Compound Q&A

What precautions should be taken when handling 6-Bromoimidazo[1,2-a]pyridin-8-amine (CAS: 676371-00-9)?

When handling 6-Bromoimidazo[1,2-a]pyridin-8-amine, it is important to wear appr...

676371-00-96-Bromoimidazo[1,2-a...
Compound Q&A

Are there alternatives to (2S,4R)-4-(4-Nitrobenzyl)pyrrolidine-2-carboxylic acid hydrochloride (CAS: 1049740-22-8) in synthesis?

Alternatives to (2S,4R)-4-(4-Nitrobenzyl)pyrrolidine-2-carboxylic acid hydrochlo...

1049740-22-8(2S,4R)-4-(4-Nitrobe...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.