Facile assembly of bifunctional, magnetically retrievable mesoporous silica for enantioselective cascade reactions

Literature Information

Publication Date 2019-10-12
DOI 10.1039/C9CC07123G
Impact Factor 6.222
Authors

Zhongrui Zhao, Fengwei Chang, Tao Wang, Lijian Wang, Lingbo Zhao, Cheng Peng, Guohua Liu


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Abstract

An integrated immobilization to encapsulate the Pd/C-coated magnetic nanoparticles within the chiral Ru/diamine-functionalized silica shell for the construction of a bifunctional magnetic catalyst is developed. This catalyst realizes a synergistic Suzuki cross-coupling/asymmetric transfer hydrogenation and a successive reduction/asymmetric transfer hydrogenation for the preparation of chiral aromatic alcohols.

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