5-(6-Methoxy-1-benzofuran-2-yl)-2-(3-methyl-2-buten-1-yl)-1,3-benzenediol
CAS Number:
1017277-40-5
Molecular Formula:
C20H20O4
Squarylium dye and onium salts as highly sensitive photoradical generators for blue light
Literature Information
Publication Date
2017-05-02
DOI
10.1039/C7PY00621G
Impact Factor
5.582
Authors
Katarzyna Kostrzewska, Joanna Ortyl, Robert Dobosz, Janina Kabatc
View Original
Abstract
2-Ethyl-2-(hydroxymethyl)-1,3-propanediol triacrylate was polymerized in the presence of squarylium dye and various onium salts. The onium salts under study are commercially available or may be easily synthesized and are characterized by light absorption properties below 300 nm and generate phenyl radicals upon blue light exposure. Due to these interesting properties the triacrylate polymerization can be efficiently carried out with or without the presence of any additional photoinitiator. The chemical mechanisms are investigated by steady state photolysis and nanosecond laser flash photolysis experiments. The new photoinitiators yielded a higher visible light photoinitiating polymerization effect than the commercial photoinitiator: camphorquinone/ethyl p-(dimethylamino)benzoate and camphorquinone/N-methyldiethanolamine under experimental conditions.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
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(5Z,11alpha,13E,15R)-11,15-Dihydroxy-15-methyl-9-oxoprosta-5,13-dien-1-oic acid
CAS Number:
55028-70-1
Molecular Formula:
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