A general method of Suzuki–Miyaura cross-coupling of 4- and 5-halo-1,2,3-triazoles in water
Literature Information
Publication Date
2017-10-31
DOI
10.1039/C7OB02091K
Impact Factor
3.876
Authors
Gleb A. Chesnokov
View Original
Abstract
A general method of the synthesis of 1,4,5-trisubstituted-1,2,3-triazoles by Suzuki–Miyaura cross-coupling from 4- and 5-halo-1,2,3-triazoles is reported. The reaction is mediated by an expanded-ring N-heterocyclic carbene palladium complex in water. The developed reaction protocol meets the requirements of “green chemistry”. Cross-coupling of 4- and 5-chlorotriazoles is reported for the first time.
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Organic & Biomolecular Chemistry
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