Colorimetric and fluorimetric response of Schiff base molecules towards fluoride anion, solution test kit fabrication, logical interpretations and DFT-D3 study

Literature Information

Publication Date 2015-07-02
DOI 10.1039/C5CP02525G
Impact Factor 3.676
Authors

Pritam Ghosh, Biswajit Gopal Roy, Saibal Jana, Subhra Kanti Mukhopadhyay


View Original

Abstract

Two newly synthesized Schiff base molecules are herein reported as anion sensors. –NO2 substituted receptor (P1) is comparatively more acidic and can sense F−, OAc− and H2PO4−, whereas –CN substituted receptor (P2) is less acidic and is selective for F− only. Reversible UV-Vis response for both receptors with F− can mimic multiple logic gate functions, and several complex electronic circuits based on XNOR, XOR, OR, AND, NOT and NOR logic operations with ‘Write–Read–Erase–Read’ options have been executed. Interesting ‘turn on and off’ fluorescence responses were noticed for the receptors with F−. Intracellular F− detection as a diagnosis of non-skeletal fluorosis was successful using a fluorescence microscope with Candida albicans (prokaryotic cell, a diploid fungus) and pollen grains of Tecoma stans (eukaryotic cell) incubated in 10−6 M fluoride-contaminated hand-pump water collected from Bankura, West Bengal, India. Furthermore, a solution test kit was fabricated for easy and selective detection of F− in an aqueous solvent.

Related Literature

Chemical bonding in cuprous complexes with simple nitriles: octet rule and resonance concepts versus quantitative charge-redistribution analysis

Simone Potenti, Lorenzo Paoloni, Surajit Nandi, Marco Fusè

2020-06-19 Paper

DOI: 10.1039/D0CP01536A

Large-scale comparison of 3d and 4d transition metal complexes illuminates the reduced effect of exchange on second-row spin-state energetics

Daniel B. K. Chu, Naveen Arunachalam, Yael Cytter, Heather J. Kulik

2020-08-10 Paper

DOI: 10.1039/D0CP02977G

Probing the binding modes and dynamics of histidine on fumed silica surfaces by solid-state NMR

Haley L. Swanson, Chengchen Guo, Michael Cao, J. Bennett Addison, Gregory P. Holland

2020-08-27 Paper

DOI: 10.1039/D0CP03472J

Understanding the g-tensors of perchlorotriphenylmethyl and Finland-type trityl radicals

Paul Demay-Drouhard, H. Y. Vincent Ching, Christophe Decroos, Régis Guillot, Yun Li, Leandro C. Tabares, Clotilde Policar, Helene C. Bertrand, Sun Un

2020-09-03 Paper

DOI: 10.1039/D0CP03626A

How Parkinson's disease-related mutations disrupt the dimerization of WD40 domain in LRRK2: a comparative molecular dynamics simulation study

Xinyi Li, Mingyu Ye, Yue Wang, Ming Qiu, Tingting Fu, Jian Zhang, Bin Zhou, Shaoyong Lu

2020-08-25 Paper

DOI: 10.1039/D0CP03171B

On the elaboration of the next generation of thermodynamic models of solid solutions

Jean-Philippe Harvey, Äimen E. Gheribi, Antoine Rincent, Javier Jofré, Paul Lafaye

2020-09-01 Paper

DOI: 10.1039/D0CP02642E

Unraveling the solvation geometries of the lanthanum(iii) bistriflimide salt in ionic liquid/acetonitrile mixtures

Valentina Migliorati, Andrea Lapi, Paola D'Angelo

2020-09-07 Paper

DOI: 10.1039/D0CP03977B

Theoretical assessment of vibrationally resolved C1s X-ray photoelectron spectra of simple cyclic molecules

Weijie Hua, Guangjun Tian, Yi Luo

2020-08-13 Paper

DOI: 10.1039/D0CP02970J

One-electron redox kinetics of aqueous transition metal couples Zn2+/+, Co2+/+, and Ni2+/+ using pulse radiolysis

Alexandra Lisovskaya, Kotchaphan Kanjana, David M. Bartels

2020-07-27 Paper

DOI: 10.1039/D0CP03214J

You might also like

Compound Q&A

How should waste containing N-Methoxy-N-methyl-1,3-thiazole-5-carboxamide (CAS: 898825-89-3) be handled?

Waste containing N-Methoxy-N-methyl-1,3-thiazole-5-carboxamide (CAS: 898825-89-3...

898825-89-3N-Methoxy-N-methyl-1...
Compound Q&A

How should N-(4-Biphenylyl)dibenzo[b,d]furan-4-amine (CAS: 1318338-47-4) be stored?

N-(4-Biphenylyl)dibenzo[b,d]furan-4-amine should be stored in a tightly sealed c...

1318338-47-4N-(4-Biphenylyl)dibe...
Compound Q&A

What is the market or research trend for 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid (CAS: 1713-07-1)?

The market for 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid (CAS: 1713-07-1) is...

1713-07-13-Acetamido-5-amino-...
Compound Q&A

How should Benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-galactopyranoside (CAS: 61820-03-9) be stored?

Benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-galactopyranoside (CAS: 61820-03-9) ...

61820-03-9Benzyl 2-O-acetyl-3,...
Compound Q&A

What regulatory guidelines apply to 2-Ethylpiperazine dihydrochloride (CAS: 438050-52-3)?

2-Ethylpiperazine dihydrochloride (CAS: 438050-52-3) is regulated under the Glob...

438050-52-32-Ethylpiperazine di...
Compound Q&A

What regulatory guidelines apply to 1,1'-[1,3-Phenylenebis(methylene)]bis(3-methyl-1H-pyrrole-2,5-dione) (CAS: 119462-56-5)?

1,1'-[1,3-Phenylenebis(methylene)]bis(3-methyl-1H-pyrrole-2,5-dione) (CAS: 11946...

119462-56-51,1'-[1,3-Phenyleneb...
Compound Q&A

Are there alternatives to 5-Fluoro-2-(1-pyrrolidinyl)pyridine (CAS: 1287217-79-1) in synthesis?

Several alternatives can be used in the synthesis of 5-Fluoro-2-(1-pyrrolidinyl)...

1287217-79-15-Fluoro-2-(1-pyrrol...
Compound Q&A

What precautions should be taken when handling 6-Bromoimidazo[1,2-a]pyridin-8-amine (CAS: 676371-00-9)?

When handling 6-Bromoimidazo[1,2-a]pyridin-8-amine, it is important to wear appr...

676371-00-96-Bromoimidazo[1,2-a...
Compound Q&A

Are there alternatives to (2S,4R)-4-(4-Nitrobenzyl)pyrrolidine-2-carboxylic acid hydrochloride (CAS: 1049740-22-8) in synthesis?

Alternatives to (2S,4R)-4-(4-Nitrobenzyl)pyrrolidine-2-carboxylic acid hydrochlo...

1049740-22-8(2S,4R)-4-(4-Nitrobe...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.