Probing hydrogen-bonding in binary liquid mixtures with terahertz time-domain spectroscopy: a comparison of Debye and absorption analysis

Literature Information

Publication Date 2015-01-26
DOI 10.1039/C4CP04477K
Impact Factor 3.676
Authors

Nicholas Y. Tan, Ruoyu Li, Pierre Bräuer, Carmine D'Agostino, Lynn F. Gladden, J. Axel Zeitler


View Original

Abstract

Terahertz time-domain spectroscopy is used to explore hydrogen bonding structure and dynamics in binary liquid mixtures, spanning a range of protic–protic, protic–aprotic and aprotic–aprotic systems. A direct absorption coefficient analysis is compared against more complex Debye analysis and we observed good agreement of the two methods in determining the hydrogen bonding properties when at least one of the mixture components is protic. When both components are aprotic, we show that the trend in absorption coefficients match well with the theoretical trend in strength of hydrogen bond interactions predicted based on steric and electronic properties of the components.

Related Literature

Xanthine-based photoaffinity probes allow assessment of ligand engagement by TRPC5 channels

Claudia C. Bauer, Katie J. Simmons, Eulashini Chuntharpursat-Bon, Matthew P. Burnham, Nikil Kapur, David J. Beech

2020-09-18 Paper

DOI: 10.1039/D0CB00126K

What's all the phos about? Insights into the phosphorylation state of the RNA polymerase II C-terminal domain via mass spectrometry

Blase M. LeBlanc, R. Yvette Moreno, Edwin E. Escobar, Mukesh Kumar Venkat Ramani, Jennifer S. Brodbelt

2021-06-03 Review Article

DOI: 10.1039/D1CB00083G

Fluorescent small-molecule agonists as follicle-stimulating hormone receptor imaging tools

Sascha Hoogendoorn, Gijs H. M. van Puijvelde, Gijs A. van der Marel, Chris J. van Koppen, C. Marco Timmers, Herman S. Overkleeft

2020-08-03 Paper

DOI: 10.1039/D0CB00068J

Modified internucleoside linkages for nuclease-resistant oligonucleotides

Guillaume Clavé, Maeva Reverte, Jean-Jacques Vasseur, Michael Smietana

2020-12-08 Review Article

DOI: 10.1039/D0CB00136H

Enhancing the enthalpic contribution of hydrogen bonds by solvent shielding

Jonathan Cramer, Xiaohua Jiang, Wojciech Schönemann, Marleen Silbermann, Pascal Zihlmann, Stefan Siegrist, Brigitte Fiege, Roman Peter Jakob, Said Rabbani, Timm Maier, Beat Ernst

2020-08-28 Paper

DOI: 10.1039/D0CB00108B

Identification of fragments binding to SARS-CoV-2 nsp10 reveals ligand-binding sites in conserved interfaces between nsp10 and nsp14/nsp16

Frank Kozielski, Céleste Sele, Vladimir O. Talibov, Jiaqi Lou, Danni Dong, Qian Wang, Xinyue Shi, Maria Nyblom, Annika Rogstam, Tobias Krojer, Wolfgang Knecht

2021-10-06 Paper

DOI: 10.1039/D1CB00135C

Contents list

Front/Back Matter

DOI: 10.1039/D0CB90003F

Advances in single-cell multi-omics profiling

Dongsheng Bai, Jinying Peng

2021-01-20 Review Article

DOI: 10.1039/D0CB00163E

Front cover

2022-01-05 Cover

DOI: 10.1039/D2CB90001G

You might also like

Compound Q&A

How should waste containing N-Methoxy-N-methyl-1,3-thiazole-5-carboxamide (CAS: 898825-89-3) be handled?

Waste containing N-Methoxy-N-methyl-1,3-thiazole-5-carboxamide (CAS: 898825-89-3...

898825-89-3N-Methoxy-N-methyl-1...
Compound Q&A

How should N-(4-Biphenylyl)dibenzo[b,d]furan-4-amine (CAS: 1318338-47-4) be stored?

N-(4-Biphenylyl)dibenzo[b,d]furan-4-amine should be stored in a tightly sealed c...

1318338-47-4N-(4-Biphenylyl)dibe...
Compound Q&A

What is the market or research trend for 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid (CAS: 1713-07-1)?

The market for 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid (CAS: 1713-07-1) is...

1713-07-13-Acetamido-5-amino-...
Compound Q&A

How should Benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-galactopyranoside (CAS: 61820-03-9) be stored?

Benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-galactopyranoside (CAS: 61820-03-9) ...

61820-03-9Benzyl 2-O-acetyl-3,...
Compound Q&A

What regulatory guidelines apply to 2-Ethylpiperazine dihydrochloride (CAS: 438050-52-3)?

2-Ethylpiperazine dihydrochloride (CAS: 438050-52-3) is regulated under the Glob...

438050-52-32-Ethylpiperazine di...
Compound Q&A

What regulatory guidelines apply to 1,1'-[1,3-Phenylenebis(methylene)]bis(3-methyl-1H-pyrrole-2,5-dione) (CAS: 119462-56-5)?

1,1'-[1,3-Phenylenebis(methylene)]bis(3-methyl-1H-pyrrole-2,5-dione) (CAS: 11946...

119462-56-51,1'-[1,3-Phenyleneb...
Compound Q&A

Are there alternatives to 5-Fluoro-2-(1-pyrrolidinyl)pyridine (CAS: 1287217-79-1) in synthesis?

Several alternatives can be used in the synthesis of 5-Fluoro-2-(1-pyrrolidinyl)...

1287217-79-15-Fluoro-2-(1-pyrrol...
Compound Q&A

What precautions should be taken when handling 6-Bromoimidazo[1,2-a]pyridin-8-amine (CAS: 676371-00-9)?

When handling 6-Bromoimidazo[1,2-a]pyridin-8-amine, it is important to wear appr...

676371-00-96-Bromoimidazo[1,2-a...
Compound Q&A

Are there alternatives to (2S,4R)-4-(4-Nitrobenzyl)pyrrolidine-2-carboxylic acid hydrochloride (CAS: 1049740-22-8) in synthesis?

Alternatives to (2S,4R)-4-(4-Nitrobenzyl)pyrrolidine-2-carboxylic acid hydrochlo...

1049740-22-8(2S,4R)-4-(4-Nitrobe...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.