Strong enhancement of parity violation effects in chiral uranium compounds

Literature Information

Publication Date 2014-06-27
DOI 10.1039/C4CP01904K
Impact Factor 3.676
Authors

Michael Wormit, Małgorzata Olejniczak, Anna-Lena Deppenmeier, Trond Saue, Peter Schwerdtfeger


View Original

Abstract

The effects of parity violation (PV) on the vibrational transitions of chiral uranium compounds of the type NUXYZ and NUHXY (X, Y, Z = F, Cl, Br, I) are analysed by means of exact two-component relativistic (X2C) Hartree–Fock and density functional calculations using NUFClI and NUHFI as representative examples. The PV contributions to the vibrational transitions were found to be in the Hz range, larger than for any of the earlier proposed chiral molecules. Thus, these systems are very promising candidates for future experimental PV measurements. A detailed comparison of the NUHFI and the NWHFI homologues reveals that subtle electronic structure effects, rather than exclusively a simple Z5 scaling law, are the cause of the strong enhancement in PV contributions of the chiral uranium molecules.

Related Literature

Effects of the Hofmeister series of sodium salts on the solvent properties of water

L. A. Ferreira, V. N. Uversky, B. Y. Zaslavsky

2017-01-09 Paper

DOI: 10.1039/C6CP08214A

Influence of Zn on the photoluminescence of colloidal (AgIn)xZn2(1−x)S2 nanocrystals

Dharmendar Kumar Sharma, Shuzo Hirata, Lukasz Bujak, Vasudevanpillai Biju, Tatsuya Kameyama, Marino Kishi, Tsukasa Torimoto, Martin Vacha

2017-01-05 Paper

DOI: 10.1039/C6CP07550A

Enhanced selective oxidation of h-BN nanosheet through a substrate-mediated localized charge effect

Xiaojun Wu, Jinlong Yang

2017-01-12 Paper

DOI: 10.1039/C6CP07402B

Mechanistic insights into CO2 reduction on Cu/Mo-loaded two-dimensional g-C3N4(001)

Penghui Li, Fang Wang, Shiqian Wei, Xinyu Li

2017-01-09 Paper

DOI: 10.1039/C6CP08409E

Exciton-vibrational resonance and dynamics of charge separation in the photosystem II reaction center

Vladimir I. Novoderezhkin, Elisabet Romero, Javier Prior, Rienk van Grondelle

2017-01-17 Paper

DOI: 10.1039/C6CP07308E

Suitability of N-propanoic acid spiropyrans and spirooxazines for use as sensitizing dyes in dye-sensitized solar cells

Noah M. Johnson, Yuriy Y. Smolin, Daniel Hagaman, Masoud Soroush, Kenneth K. S. Lau, Hai-Feng Ji

2017-01-04 Paper

DOI: 10.1039/C6CP07853B

Role of polar side chains in Li+ coordination and transport properties of polyoxetane-based polymer electrolytes

Ryansu Sai, Kazuhide Ueno, Kenta Fujii, Yohei Nakano, Naho Shigaki, Hiromori Tsutsumi

2017-01-23 Paper

DOI: 10.1039/C6CP08386B

You might also like

Compound Q&A

What are the main uses of (5-Sulfamoyl-3-pyridinyl)boronic acid (CAS: 951233-61-7)?

(5-Sulfamoyl-3-pyridinyl)boronic acid is primarily used in chemical synthesis, p...

951233-61-7(5-Sulfamoyl-3-pyrid...
Compound Q&A

How is Benzyl 2-methyl-2-(methylsulfonyl)-4-pentenoate (CAS: 1942858-50-5) typically synthesized?

Benzyl 2-methyl-2-(methylsulfonyl)-4-pentenoate is typically synthesized via est...

1942858-50-5Benzyl 2-methyl-2-(m...
Compound Q&A

What precautions should be taken when handling 8-Fluoroquinolin-6-ol (CAS: 209353-22-0)?

When handling 8-Fluoroquinolin-6-ol (CAS: 209353-22-0), it is important to use p...

209353-22-08-Fluoroquinolin-6-o...
Compound Q&A

What are the physical and chemical properties of 1,3-Dibromo-5-(2-methyl-2-propanyl)benzene (CAS: 129316-09-2)?

1,3-Dibromo-5-(2-methyl-2-propanyl)benzene (CAS: 129316-09-2) is a crystalline c...

129316-09-21,3-Dibromo-5-(2-met...
Compound Q&A

What industries use Ethyl 7-chloro-4-oxo-1-(1,3-thiazol-2-yl)-1,4-dihydro-1,8-naphthyridine-3-carboxylate (CAS: 174726-87-5)?

Ethyl 7-chloro-4-oxo-1-(1,3-thiazol-2-yl)-1,4-dihydro-1,8-naphthyridine-3-carbox...

174726-87-5Ethyl 7-chloro-4-oxo...
Compound Q&A

What precautions should be taken when handling Delta-7-Avenasterol (CAS: 23290-26-8)?

When handling Delta-7-Avenasterol (CAS: 23290-26-8), it is important to wear app...

23290-26-8Delta-7-Avenasterol
872992-20-6N-({(5R)-3-[3-Fluoro...
Compound Q&A

What precautions should be taken when handling 2-Methyl-2-proanyl 4-[(2-aminophenyl)amino]-1-piperidinecarboxylate (CAS: 79099-00-6)?

When handling 2-Methyl-2-proanyl 4-[(2-aminophenyl)amino]-1-piperidinecarboxylat...

79099-00-62-Methyl-2-propanyl ...
Compound Q&A

What is N-Methyl-4-chlorobenzylamine hydrochloride (CAS: 65542-24-7)?

N-Methyl-4-chlorobenzylamine hydrochloride (CAS: 65542-24-7) is a organic compou...

65542-24-7N-Methyl-4-chloroben...
Compound Q&A

Is [2-(Dodecyloxy)ethoxy]acetic acid (CAS: 27306-90-7) safe?

[2-(Dodecyloxy)ethoxy]acetic acid (CAS: 27306-90-7) is generally considered safe...

27306-90-7[2-(Dodecyloxy)ethox...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.