En route to traceable reference standards for surface group quantifications by XPS, NMR and fluorescence spectroscopy

Literature Information

Publication Date 2015-01-28
DOI 10.1039/C4AN02248C
Impact Factor 4.616
Authors

Paul M. Dietrich, Felix Hemmann, Thomas Thiele, Heike Borcherding, Angelika Hoffmann, Uwe Schedler, Christian Jäger, Ute Resch-Genger, Wolfgang E. S. Unger


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Abstract

The fluorine content of polymer particles labelled with 2,2,2-trifluoroethylamine was reliably quantified with overlapping sensitivity ranges by XPS and solid-state NMR. This provides a first step towards reference materials for the metrological traceability of surface group quantifications. The extension of this concept to fluorescence spectroscopy is illustrated.

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