Flexible H-bonded liquid-crystals with wide enantiotropic blue phases
Literature Information
Wan-Li He, Mei-Ju Wei, Zhou Yang, Hui Cao, Dong Wang
Novel cinnamic-acid-derived H-bonded liquid crystals with enantiotropic BP*s were facilely prepared. When simply modifying the donor–acceptor ratio, the proportion of (S)-4-(2-octanyloxy) cinnamic acid to 4-(4-propylcyclohexyl) phenyl isonicotinate, the generated BP temperature ranges were consequentially extended with the widest range of about 10 °C, which is seldom found in enantiotropic BP materials. The optimized results of density-functional-theory calculations show that cinnamic-acid-derived mesogens have a bent shape and thus could be beneficial to stabilize enantiotropic blue phases.
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Physical Chemistry Chemical Physics

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