Outer Co(ii) ions in Co-ZIF-67 reversibly adsorb oxygen from both gas phase and liquid water

Literature Information

Publication Date 2014-01-13
DOI 10.1039/C3CP54896A
Impact Factor 3.676
Authors

Guido Saracco, Svetoslava Vankova, Cristina Pagliano, Barbara Bonelli, Edoardo Garrone


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Abstract

Outer Co(II) species in Co-ZIF-67 coordinate molecular oxygen both from the gas phase and liquid water, through an adsorption process (presumably yielding in both cases surface superoxo species), respectively weak and reversible (gas phase), and strong and irreversible (liquid); in the latter case desorption is however brought about by illumination with solar light comprising the UV component.

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Physical Chemistry Chemical Physics
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