Energetic behavior of the pure silica ITQ-12 (ITW) zeolite under high pressure water intrusion

Literature Information

Publication Date 2013-10-15
DOI 10.1039/C3CP53570C
Impact Factor 3.676
Authors

Ismail Khay, Lydie Tzanis, T. Jean Daou, Habiba Nouali, Andrey Ryzhikov, Joël Patarin


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Abstract

Experimental water intrusion–extrusion isotherms were obtained at room temperature on pure silica ITW-type zeolites (ITQ-12 zeosil). The water intrusion is obtained by applying a high hydraulic pressure corresponding to the intrusion step. When the pressure is released, the water extrusion occurs at a similar pressure to that of the intrusion one. Therefore, the “ITW zeosil–water” system behaves like a spring and the phenomenon is reproducible over several cycles. Several characterization techniques have been performed before and after water intrusion–extrusion experiments in order to reveal the presence or the lack of defects after such experiments. Structural modifications at the long range order cannot be observed by XRD analysis after three water intrusion–extrusion cycles. However, solid state NMR spectroscopy provides evidence of the presence of Q3 groups revealing the breaking of some siloxane bridges after the intrusion step. The “ITW zeosil–water” system can restore 100% of the stored energy corresponding to about 8 J g−1.

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Inside front cover

2023-11-22 Cover

DOI: 10.1039/D3CP90233A

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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