Miktoarm star polymersviacyclodextrin-driven supramolecular self-assembly
Literature Information
Publication Date
2012-06-13
DOI
10.1039/C2PY20214J
Impact Factor
5.582
Authors
Bernhard V. K. J. Schmidt, Martin Hetzer, Helmut Ritter, Christopher Barner-Kowollik
View Original
Abstract
We report the formation of a novel class of supramolecular miktoarm star polymers via cyclodextrin host–guest chemistry. Reversible addition–fragmentation chain transfer polymerization from difunctional guest- or alkyne-containing chain transfer agents and copper(I)-catalyzed azide–alkyne cycloaddition leads to host- and guest-containing acrylamido polymers, namely poly(N,N-dimethylacrylamide) and poly(N,N-diethylacrylamide). Subsequently, a supramolecular miktoarm star polymer was formed and characterized via dynamic light scattering and rotating frame nuclear Overhauser effect spectroscopy.
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Source Journal
Polymer Chemistry
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