Rovibrational levels of HD
Literature Information
Krzysztof Pachucki, Jacek Komasa
The dissociation energies of all rotation–vibrational states of the molecular HD in the ground electronic state are calculated to a high accuracy by including nonadiabatic, relativistic α2, and quantum electrodynamic α3 effects, with approximate treatment of small higher order α4, and finite nuclear size corrections. The obtained result for the ground molecular state of 36 405.7828(10) cm−1 is in a small disagreement with the latest most precise experimental value.
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