Synthesis of transition metal isocyanide compounds from carbonyl complexes via reaction with Li[Me3SiNR]‡

Literature Information

Publication Date 2009-11-12
DOI 10.1039/B917156H
Impact Factor 6.222
Authors

Wesley Sattler, Gerard Parkin


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Abstract

The reaction between a transition metal carbonyl compound, LnMCO, and Li[Me3SiNR] yields the corresponding isocyanide derivative, LnMCNR, thereby providing a new route to transition metal isocyanide compounds that does not require the use of free isocyanides as reagents.

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