In situSTM investigation of the lithium underpotential deposition on Au(111) in the air- and water-stable ionic liquid 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide
Literature Information
N. Bocchi
In the present paper the underpotential deposition (UPD) of lithium on Au(111) from 0.5 mol L−1LiTFSA in the air- and water stable ionic liquid 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide, [Py1,4]TFSA, has been investigated by cyclic voltammetry (CV) and in situ scanning tunneling microscopy (STM). The pure [Py1,4]TFSA was found to be inert in the potential regime investigated. The results show that the lithium UPD on Au(111) in [Py1,4]TFSA begins at potentials considerably positive to the electrode potential of bulk deposition and follows a layer-by-layer mechanism with the formation of at least two monolayers. A large number of monoatomically deep pits appear when the potential reaches positive values, which is an indication that a Li–Au alloy was formed.
Related Literature
Charge transfer process at the Ag/MPH/TiO2 interface by SERS: alignment of the Fermi level
Xiaolei Zhang, Huimin Sui, Xiaolei Wang, Hongyang Su, Weina Cheng, Xu Wang, Bing Zhao
DOI: 10.1039/C6CP04370D
Deprotonation of formic acid in collisions with a liquid water surface studied by molecular dynamics and metadynamics simulations
Garold Murdachaew, Gilbert M. Nathanson, Lauri Halonen
DOI: 10.1039/C6CP06071D
Stacking disorder in silicon carbide supported cobalt crystallites: an X-ray diffraction, electron diffraction and high resolution electron microscopy study
H. E. du Plessis, J. P. R. de Villiers, A. Tuling, E. J. Olivier
DOI: 10.1039/C6CP06334A
The temperature dependence of the Hofmeister series: thermodynamic fingerprints of cosolute–protein interactions
Michael Senske, Diana Constantinescu-Aruxandei, Martina Havenith, Christian Herrmann, Hermann Weingärtner, Simon Ebbinghaus
DOI: 10.1039/C6CP05080H
A highly efficient g-C3N4/SiO2 heterojunction: the role of SiO2 in the enhancement of visible light photocatalytic activity
Qiang Hao, Xiuxiu Niu, Changshun Nie, Simeng Hao, Wei Zou, Jiangman Ge, Daimei Chen, Wenqing Yao
DOI: 10.1039/C6CP06122B
High-performance printable hybrid perovskite solar cells with an easily accessible n-doped fullerene as a cathode interfacial layer
Chih-Yu Chang, Bo-Chou Tsai, Yu-Cheng Hsiao, Yu-Ching Huang
DOI: 10.1039/C6CP06486H
Rotational dynamics of Li+ ions encapsulated in C60 cages at low temperatures
Hal Suzuki, Misaki Ishida, Masatsugu Yamashita, Chiko Otani, Kazuhiko Kawachi, Yasuhiko Kasama, Eunsang Kwon
DOI: 10.1039/C6CP06949E
Direct observation of ice nucleation events on individual atmospheric particles
Bingbing Wang, Daniel A. Knopf, Swarup China, Bruce W. Arey, Mary K. Gilles, Alexander Laskin
DOI: 10.1039/C6CP05253C
Salt gradient driven ion transport in solid-state nanopores: the crucial role of reservoir geometry and size
Chih-Yuan Lin, Fu Chen, Li-Hsien Yeh, Jyh-Ping Hsu
DOI: 10.1039/C6CP06459K
Oxidation of multicarbon compounds to CO2 by photocatalysts with energy storage abilities
Yoshinori Kuroiwa, Susie Park, Tetsu Tatsuma
DOI: 10.1039/C6CP06973H
You might also like
What precautions should be taken when handling 2-Chloro-1,2-bis(4-methylphenyl)ethanone (CAS: 71193-32-3)?
When handling 2-Chloro-1,2-bis(4-methylphenyl)ethanone (CAS: 71193-32-3), it is ...
What industries use 4-Ethoxy-3-(5-methyl-4-oxo-7-propyl-1,4-dihydroimidazo[5,1-f][1,2,4]triazin-2-yl)benzenesulfonyl chloride (CAS: 224789-26-8)?
4-Ethoxy-3-(5-methyl-4-oxo-7-propyl-1,4-dihydroimidazo[5,1-f][1,2,4]triazin-2-yl...
How should Methyl 3-Oxo-4-Androsten-17-Carboxylate (CAS: 2681-55-2) be stored?
Methyl 3-Oxo-4-Androsten-17-Carboxylate (CAS: 2681-55-2) should be stored in a c...
What are the main uses of (R)-3-Amino-4-(3-hexylphenylamino)-4-oxobutylphosphonic acid (CAS: 909725-61-7)?
(R)-3-Amino-4-(3-hexylphenylamino)-4-oxobutylphosphonic acid is primarily used i...
What regulatory guidelines apply to 2-Methyl-2-propanyl 3-amino-3-carbamoyl-1-azetidinecarboxylate (CAS: 1254120-14-3)?
2-Methyl-2-propanyl 3-amino-3-carbamoyl-1-azetidinecarboxylate (CAS: 1254120-14-...
Are there alternatives to (E)-4-(tert-Butoxy)-4-oxobut-2-enoic acid (CAS: 135355-96-3) in synthesis?
There are alternative reagents that can be used in synthesis instead of (E)-4-(t...
What are the physical and chemical properties of [2-(3-Chlorophenyl)-1,3-thiazol-4-yl]methanol (CAS: 121202-20-8)?
[2-(3-Chlorophenyl)-1,3-thiazol-4-yl]methanol (CAS: 121202-20-8) is a crystallin...
What is the market or research trend for Methyl (2S)-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]{[(4-methylphenyl)sulfonyl]oxy}acetate (CAS: 166249-17-8)?
The market and research trends for Methyl (2S)-[(4S)-2,2-dimethyl-1,3-dioxolan-4...
What is the market or research trend for 1-Bromo-2-isocyanatoethane (CAS: 42865-19-0)?
The market for 1-Bromo-2-isocyanatoethane (CAS: 42865-19-0) is driven by its use...
What are the main uses of 4-Nitro-D-phenylalanine hydrochloride (CAS: 147065-06-3)?
4-Nitro-D-phenylalanine hydrochloride (CAS: 147065-06-3) is primarily used in re...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











![(1R)-3-Bromo-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one structure (1R)-3-Bromo-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one structure](https://static.chemtradehub.com/structs/102/10293-06-8-dd8a.webp)


