{Ge9R3Cr(CO)5}− and {Ge9R3Cr(CO)3}−: a metalloid cluster (Ge9R3−) as a flexible ligand in coordination chemistry [R = Si(SiMe3)3]

Literature Information

Publication Date 2009-05-05
DOI 10.1039/B901870K
Impact Factor 6.222
Authors

Christian Schenk, Andreas Schnepf


View Original

Abstract

The reactions of the metalloid cluster {Ge9[Si(SiMe3)3]3}− with Cr(CO)5COE (COE = cyclooctene) and Cr(CO)3(CH3CN)3 lead to the new cluster compounds {Ge9[Si(SiMe3)3]3Cr(CO)5}− and {Ge9[Si(SiMe3)3]3Cr(CO)3}−, whose structural and electronic properties are presented.

Related Literature

New insight into the discharge mechanism of silicon–air batteries using electrochemical impedance spectroscopy

Gil Cohn, Rüdiger A. Eichel, Yair Ein-Eli

2013-01-04 Paper

DOI: 10.1039/C2CP43870D

Efficient reduction of graphene oxide catalyzed by copper

Keng-Ku Liu, Chih-Yu Wu, Chih-Wei Chu, Jacob Tse-Wei Wang, Chi-Te Liang

2011-12-21 Paper

DOI: 10.1039/C2CP23187E

Efficient energy transfer from InGaN quantum wells to Ag nanoparticles

G. W. Shu, C. H. Chiu, L. T. Huang, T. N. Lin, C. C. Yang, J. S. Wang, C. T. Yuan, J. L. Shen, H. C. Kuo, C. A. J. Lin, W. H. Chang, H. H. Wang, H. I. Yeh, W. H. Chan, W. C. Fan, W. C. Chou

2013-02-04 Paper

DOI: 10.1039/C3CP43894E

The trehalose coating effect on the internal protein dynamics

Christiane Hackel, Tatyana Zinkevich, Peter Belton, Anja Achilles, Detlef Reichert

2012-01-19 Paper

DOI: 10.1039/C2CP23098D

Front cover

Cover

DOI: 10.1039/C2CP90012B

Nanoporous silicon networks as anodes for lithium ion batteries

Jia Zhu, Christopher Gladden, Nian Liu, Yi Cui, Xiang Zhang

2012-11-15 Communication

DOI: 10.1039/C2CP44046F

Electrode screening by ionic liquids

R. M. Lynden-Bell, A. I. Frolov, M. V. Fedorov

2011-12-19 Paper

DOI: 10.1039/C2CP23267G

Effect of potential on temperature-dependent SERS spectra of neuromedin B on Cu electrode

Ilja Ignatjev, Edyta Proniewicz, Leonard M. Proniewicz, Gediminas Niaura

2012-11-16 Paper

DOI: 10.1039/C2CP42077E

Quantum chemical study of the catalytic activation of methane by copper oxide and copper hydroxide cations

E. Rezabal, F. Ruipérez, J. M. Ugalde

2012-11-19 Paper

DOI: 10.1039/C2CP43544F

You might also like

Compound Q&A

How should 2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) be stored?

2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) should be stored in ...

615-45-22-Methylbenzene-1,4-...
Compound Q&A

Is (1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide (CAS: 132747-20-7) safe?

(1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide is generally considered sa...

132747-20-7(1S,4S)-2,5-Diazabic...
Compound Q&A

What industries use (6-Chloropyridazin-3-YL)methanamine (CAS: 871826-15-2)?

(6-Chloropyridazin-3-YL)methanamine finds applications in the pharmaceutical ind...

871826-15-2(6-Chloropyridazin-3...
Compound Q&A

What are the main uses of 2-Fluoro-3-methylphenol (CAS: 77772-72-6)?

2-Fluoro-3-methylphenol is primarily used in the synthesis of pharmaceuticals, p...

77772-72-62-Fluoro-3-methylphe...
Compound Q&A

What precautions should be taken when handling 3-Methoxy-4-nitrobenzonitrile (CAS: 177476-75-4)?

When handling 3-Methoxy-4-nitrobenzonitrile, it is important to wear appropriate...

177476-75-43-Methoxy-4-nitroben...
Compound Q&A

What precautions should be taken when handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4)?

When handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4), it is ...

211949-57-4[1,3]Oxazolo[4,5-b]p...
Compound Q&A

What regulatory guidelines apply to 4-Ethynylbenzamide (CAS: 90347-86-7)?

4-Ethynylbenzamide (CAS: 90347-86-7) falls under various regulatory guidelines i...

90347-86-74-Ethynylbenzamide
Compound Q&A

What are the main uses of 3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone (CAS: 186822-57-1)?

3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone is primarily used as an intermediat...

186822-57-13-(2-Ethylphenyl)-2-...
Compound Q&A

What is (2-Fluoro-6-methoxyphenyl)acetic acid (CAS: 500912-19-6)?

(2-Fluoro-6-methoxyphenyl)acetic acid, also known as 4-fluoro-3-methoxybenzoic a...

500912-19-6(2-Fluoro-6-methoxyp...
Compound Q&A

What is the market or research trend for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9)?

Market trends for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9) indicat...

102196-18-92-[4-(Hydroxymethyl)...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.