Temperature control of pattern formation in the Ru(bpy)32+-catalyzed BZ-AOT system
Literature Information
Rachel McIlwaine, Vladimir K. Vanag, Irving R. Epstein
Using temperature as a control parameter, we observe a transition from stationary Turing patterns at T = 15–20 °C to traveling waves at T = 50 °C (and above) in the Ru(bpy)32+-catalyzed Belousov–Zhabotinsky (BZ) reaction incorporated into the water nanodroplets of a water-in-oil aerosol OT (AOT) microemulsion. At constant chemical composition, molar ratio and droplet fraction, the transition takes place via a series of stable patterns, including oscillatory Turing patterns (at 35–40 °C) and reversed oscillatory Turing patterns (at 50 °C). We attribute the pattern transitions to a temperature-induced percolation transition of the BZ-AOT microemulsion, implying a change from isolated water nanodroplets to a system-spanning network of water channels.
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