Synthesis of poly(vinyl acetate) block copolymers by successive RAFT and ATRP with a bromoxanthate iniferter

Literature Information

Publication Date 2008-09-18
DOI 10.1039/B810778E
Impact Factor 6.222
Authors

Renaud Nicolaÿ, Yungwan Kwak, Krzysztof Matyjaszewski


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Abstract

Poly(vinyl acetate)-b-polystyrene, poly(vinyl acetate)-b-poly(methyl acrylate) and poly(vinyl acetate)-b-poly(methyl methacrylate) block copolymers with low polydispersity (Mw/Mn < 1.25) were prepared by successive reversible addition–fragmentation chain transfer (RAFT) polymerization and atom transfer radical polymerization (ATRP) employing a bromoxanthateiniferter (initiator-transfer agent-terminator).

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