Binuclear organometallic ruthenium complexes of a Schiff base expanded porphyrin

Literature Information

Publication Date 2008-07-01
DOI 10.1039/B807126H
Impact Factor 6.222
Authors

Luciano Cuesta, Elisa Tomat, Vincent M. Lynch, Jonathan L. Sessler


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Abstract

The synthesis of binuclear organometallic ruthenium complexes of an expanded porphyrin-type macrocycle is reported; pyrrolic hydrogen bonding donors were found to interact with ancillary ligands in the primary coordination sphere and to stabilize coordinated dioxygen in an η2-fashion.

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