X-Shaped polyphilics: liquid crystal honeycombs with single-molecule walls

Literature Information

Publication Date 2008-05-20
DOI 10.1039/B804945A
Impact Factor 6.222
Authors

Robert Kieffer, Benjamin Glettner, Karsten Pelz, Ute Baumeister, Feng Liu, Xiangbing Zeng, Goran Ungar, Carsten Tschierske


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Abstract

X-Shaped ternary five-block molecules, composed of a rigid p-terphenyl core, two terminal glycerol groups and two flexible n-alkyl or semiperfluorinated chains fixed laterally to opposite sides of the terphenyl moiety, form liquid crystalline phases built up of honeycomb-like arrays of polygonal cylinders, where the rod-like aromatic cores form cylinder walls with a thickness equal to the width of a single molecule.

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