Direct generation of hydrogen peroxide from formic acid and O2 using heterogeneous Pd/γ-Al2O3catalysts

Literature Information

Publication Date 2008-06-27
DOI 10.1039/B803149E
Impact Factor 6.222
Authors

Mohammad S. Yalfani, Sandra Contreras, Francesc Medina, Jesus Sueiras


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Abstract

Hydrogen peroxide formation is achieved with remarkable productivity at ambient conditions (25 °C and atmospheric pressure) in aqueous medium using a heterogeneous catalytic system; formic acid is decomposed in the presence of a continuous flow of O2 over Pd/γ-Al2O3catalyst leading to the generation of hydrogen peroxide; the addition of a negligible amount of bromide ion improves the selectivity of the reaction.

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