Cobalt-catalyzed intermolecular C–H amination with bromamine-T as nitrene source

Literature Information

Publication Date 2007-09-03
DOI 10.1039/B710677G
Impact Factor 6.222
Authors

Jeremiah D. Harden, Joshua V. Ruppel, Guang-Yao Gao, X. Peter Zhang


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Abstract

Cobalt, supported by porphyrin ligands, is capable of catalyzing intermolecular nitrene insertion of sp3 C–H bonds with bromamine-T as the nitrene source, forming the desired tosyl-protected amines with NaBr as the by-product.

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