Solid-state luminescence switching of platinum(ii) dithiooxamide complexes in the presence of hydrogen halide and amine gases
Literature Information
Francesco Nastasi, Fausto Puntoriero, Natale Palmeri, Stefano Cavallaro, Sebastiano Campagna, Santo Lanza
In the solid state, a non-luminescent platinum(II) dithiooxamide species adsorbs gaseous HCl, yielding a tight ion pair species which exhibits photoluminescence; the process is quantitatively reversed on heating or by exposing the sample to ammonia vapors.
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