Solid-state luminescence switching of platinum(ii) dithiooxamide complexes in the presence of hydrogen halide and amine gases

Literature Information

Publication Date 2007-09-11
DOI 10.1039/B710372G
Impact Factor 6.222
Authors

Francesco Nastasi, Fausto Puntoriero, Natale Palmeri, Stefano Cavallaro, Sebastiano Campagna, Santo Lanza


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Abstract

In the solid state, a non-luminescent platinum(II) dithiooxamide species adsorbs gaseous HCl, yielding a tight ion pair species which exhibits photoluminescence; the process is quantitatively reversed on heating or by exposing the sample to ammonia vapors.

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