The dramatic acceleration effect of imidazolium ionic liquids on electron transfer reactions

Literature Information

Publication Date 2007-07-31
DOI 10.1039/B708044A
Impact Factor 6.222
Authors

Doo Seong Choi, Dong Hyun Kim, Ueon Sang Shin, Ravindra R. Deshmukh, Sang-gi Lee, Choong Eui Song


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Abstract

Imidazolium ionic liquids (ILs) exhibited a dramatic acceleration effect on the electron transfer from metal complexes such as (C5Me5)2Fe(II) and (C5Me5)2Co(II) to the oxygen molecule; this acceleration effect can be ascribed to the stabilization of the oxygen radical anions by coordinating with the acidic C2-H of imidazolium ILs.

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