Cα,Cortho-Dimetalated phosphazene complexes‡

Literature Information

Publication Date 2007-08-28
DOI 10.1039/B707320H
Impact Factor 6.222
Authors

Jesús García López, Ignacio Fernández, Manuel Serrano Ruiz, Fernando López Ortiz


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Abstract

The first Cα,Cortho dilithium complex of a phosphazene has been synthesized as a single stereoisomer and has been structurally characterized in solution; the complex is monomeric, with the dianion acting as an N–Cortho and O–Cα chelate. Transmetallation with Me3SnCl and PhHgCl afforded the first Cα,Cortho homo- and hetero-bimetallic phosphazene complexes, which contain a desymmetrised Ph2PN moiety.

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