Cα,Cortho-Dimetalated phosphazene complexes‡
Literature Information
Jesús García López, Ignacio Fernández, Manuel Serrano Ruiz, Fernando López Ortiz
The first Cα,Cortho dilithium complex of a phosphazene has been synthesized as a single stereoisomer and has been structurally characterized in solution; the complex is monomeric, with the dianion acting as an N–Cortho and O–Cα chelate. Transmetallation with Me3SnCl and PhHgCl afforded the first Cα,Cortho homo- and hetero-bimetallic phosphazene complexes, which contain a desymmetrised Ph2PN moiety.
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