pH-Induced formation of metalloligand: increasing structure dimensionality by tuning number of ligand functional sites
Literature Information
Wen-Xiu Ni, Mian Li, Xiao-Ping Zhou, Zhen Li, Xiao-Chun Huang, Dan Li
Two complexes, 2D [Cu2(CN)2(4-Hpcih)]n and 3D {[Cu2(CN)1.5(4-pcih)]·1.25H2O}n (4-Hpcih = 4-pyridinecarbaldehyde isonicotinoyl hydrazone), were obtained using a synthetic approach of pH-induced formation of metalloligands, successfully demonstrating a strategy to increase structure dimensionality by tuning the number of ligand functional sites.
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