One-step assembly of a chiral palladium bis(acyclic diaminocarbene) complex and its unexpected oxidation to a bis(amidine) complex

Literature Information

Publication Date 2007-06-11
DOI 10.1039/B703769D
Impact Factor 6.222
Authors

Yoshitha A. Wanniarachchi, LeGrande M. Slaughter


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Abstract

Addition of trans-N,N′-dimethyl-1,2-diaminocyclohexane to a palladium bis(arylisocyanide) complex leads to the one-step formation of the first chiral bis(acyclic diaminocarbene) complex, which is thermally stable under N2 but undergoes slow oxidation to a bis(amidine) complex under air.

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