Synthesis and characterization of difluoromethylene-homo[60]fullerene, C60(CF2)

Literature Information

Publication Date 2006-12-18
DOI 10.1039/B611623J
Impact Factor 6.222
Authors

Anna S. Pimenova, Andrey A. Kozlov, Alexey A. Goryunkov, Vitaliy Yu. Markov, Pavel A. Khavrel, Stanislav M. Avdoshenko, Ilya N. Ioffe, Sergey I. Troyanov, Lev N. Sidorov


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Abstract

Refluxing of the o-DCB solution of C60 with CF2ClCOONa and 18-crown-6 leads to formation of C60(CF2)n (n = 1–3); the monoadduct C60(CF2) has been found to consist of the main [6,6]- and minor [5,6]-isomers, both having an open structure.

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