Chiral azide-bridged two-dimensional Cu(ii) compounds showing a field-induced spin–flop transition

Literature Information

Publication Date 2005-07-15
DOI 10.1039/B507051A
Impact Factor 6.222
Authors

Young Sin You, Jung Hee Yoon, Hyoung Chan Kim, Chang Seop Hong


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Abstract

Two azide-bridged chiral Cu(II) compounds, [Cu(R,R-dacy)(N3)2]n (1) (R,R-dacy = trans-(1R,2R)-diaminocyclohexane) and [Cu(S,S-dacy)(N3)2]n (2) (S,S-dacy = trans-(1S,2S)-diaminocyclohexane), with two-dimensional layer structures exhibiting end-to-end and end-on azide bridging patterns, were prepared and among them 1 was examined to show a field-induced spin–flop transition.

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