First successful application of diphosphite ligands in the asymmetric hydroformylation of dihydrofurans

Literature Information

Publication Date 2005-01-19
DOI 10.1039/B416514D
Impact Factor 6.222
Authors

Montserrat Diéguez, Oscar Pamies, Carmen Claver


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Abstract

Good enantioselectivities and excellent regioselectivities are achieved in the Rh-catalyzed asymmetric hydroformylation of 2,5- and 2,3-dihydrofuran using diphosphite ligands; whereby the backbone of the ligand is crucial to suppressing isomerization and obtaining high ee's.

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