The first X-ray crystal structure determination of a dinuclear complex trapped in the [low spin–high spin] state: [FeII2(PMAT)2](BF4)4·DMF

Literature Information

Publication Date 2005-01-04
DOI 10.1039/B415891A
Impact Factor 6.222
Authors

Marco H. Klingele, Boujemaa Moubaraki, John D. Cashion, Keith S. Murray, Sally Brooker


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Abstract

The two metal centres in the doubly 1,2,4-triazole-bridged spin crossover complex [FeII2(PMAT)2](BF4)4·DMF (1·DMF) are trapped in different spin states below ca. 200 K, with no evidence that this particular [LS–HS] species can be converted into the [LS–LS] form at ambient pressure.

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DOI: 10.1039/JA99106FX001

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DOI: 10.1039/JA99005BP005

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DOI: 10.1039/JA98904BX023

Atomic spectrometry update references

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DOI: 10.1039/JA991060041R

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DOI: 10.1039/JA989040479B

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DOI: 10.1039/JA993080002N

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DOI: 10.1039/JA99106BP005

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