New chemical evidence for the ability to generate radical molecular ions of polyenes from ESI and HR-MALDI mass spectrometry
Literature Information
Publication Date
2004-10-22
DOI
10.1039/B412154F
Impact Factor
4.616
Authors
Thais Guaratini, Ricardo L. Vessecchi, Francisco C. Lavarda, Patrícia M. B. G. Maia Campos, Zeki Naal, Paul J. Gates, Norberto P. Lopes
View Original
Abstract
We report here new chemical evidence for the generation of radical molecular ions of compounds with a conjugated π-system (polyene) in ESI and HR-MALDI mass spectrometry. The oxidation potential of the neutral polyenes was calculated by cyclic-voltammetry and the results compared with those previously published for other complex conjugated compounds that have also been shown to form M˙+ in ESI-MS. This study clearly demonstrates the correlation between the oxidation potential and the formation of the M˙+ for the polyenes studied.
Related Literature
Defect chemistry and lithium transport in Li3OCl anti-perovskite superionic conductors
Chi Chen, Zarah Medina Baiyee, Xin Chen, Chunming Niu
2015-10-28
Paper
DOI: 10.1039/C5CP05722A
Theoretical analysis of NMR shieldings in XSe and XTe (X = Si, Ge, Sn and Pb): the spin-rotation constant saga
2015-12-21
Paper
DOI: 10.1039/C5CP07025B
A real-space stochastic density matrix approach for density functional electronic structure
2015-05-08
Paper
DOI: 10.1039/C5CP01222H
An auxilliary grid method for the calculation of electrostatic terms in density functional theory on a real-space grid
Michael Zuzovski, Amir Boag, Amir Natan
2015-06-30
Paper
DOI: 10.1039/C5CP01090J
Ullmann coupling mediated assembly of an electrically driven altitudinal molecular rotor
Colin J. Murphy, Zachary C. Smith, Alex Pronschinski, Emily A. Lewis, Melissa L. Liriano, Chloe Wong, Christopher J. Ivimey, Mitchell Duffy, Wojciech Musial, Andrew J. Therrien, Samuel W. Thomas III, E. Charles H. Sykes
2015-11-03
Paper
DOI: 10.1039/C5CP05294G
The influence of active site conformations on the hydride transfer step of the thymidylate synthase reaction mechanism
Amnon Kohen, Vicent Moliner
2015-04-02
Paper
DOI: 10.1039/C5CP01239B
High resolution absolute absorption cross sections of the 1A′–1A′ transition of the CH2OO biradical
Elizabeth S. Foreman, Kara M. Kapnas, YiTien Jou, Jarosław Kalinowski, David Feng, Craig Murray
2015-11-23
Paper
DOI: 10.1039/C5CP04977F
Effect of strong phonon–phonon coupling on the temperature dependent structural stability and frequency shift of 2D hexagonal boron nitride
P. Anees, M. C. Valsakumar, B. K. Panigrahi
2015-12-01
Paper
DOI: 10.1039/C5CP06111C
Influence of additives on the structure of surfactant-free microemulsions
J. Marcus, D. Touraud, S. Prévost, O. Diat, T. Zemb, W. Kunz
2015-11-18
Paper
DOI: 10.1039/C5CP06364G
You might also like
Compound Q&A
What are the main uses of 1H-Indazole-6-carbonitrile (CAS: 141290-59-7)?
1H-Indazole-6-carbonitrile finds applications in pharmaceuticals, where it serve...
141290-59-71H-Indazole-6-carbon...
Compound Q&A
How should waste containing Dioctyl (2E)-2-butenedioate (CAS: 2997-85-5) be handled?
Waste containing Dioctyl (2E)-2-butenedioate (CAS: 2997-85-5) should be collecte...
2997-85-5Dioctyl (2E)-2-buten...
Compound Q&A
What industries use Sodium [(1,2-benzoxazol-3-ylmethyl)sulfonyl]azanide (CAS: 68291-98-5)?
Sodium [(1,2-benzoxazol-3-ylmethyl)sulfonyl]azanide is primarily used in pharmac...
68291-98-5Sodium [(1,2-benzoxa...
Compound Q&A
Are there alternatives to Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,6-pyridinedicarboxylate (CAS: 741709-66-0) in synthesis?
Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,6-pyridinedicarboxyla...
741709-66-0Dimethyl 4-(4,4,5,5-...
Compound Q&A
How should waste containing 2-Fluoro-6-hydrazinopyridine (CAS: 80714-39-2) be handled?
Waste containing 2-Fluoro-6-hydrazinopyridine (CAS: 80714-39-2) should be manage...
80714-39-22-Fluoro-6-hydrazino...
Compound Q&A
What is 6-Formyl-2-pyridinecarboxylic acid (CAS: 499214-11-8)?
6-Formyl-2-pyridinecarboxylic acid is an organic compound with the molecular for...
499214-11-86-Formyl-2-pyridinec...
Compound Q&A
What is the market or research trend for 3-(3,4-dimethoxyphenyl)-2,5-dimethyl-N-(2-morpholin-4-ylethyl)pyrazolo[1,5-a]pyrimidin-7-amine (CAS: 900874-91-1)?
Research trends for this compound indicate a focus on its potential applications...
900874-91-13-(3,4-dimethoxyphen...
Compound Q&A
How is 9H-Tribenzo[b,d,f]azepine (CAS: 29875-73-8) typically synthesized?
9H-Tribenzo[b,d,f]azepine is typically synthesized via a multi-step process invo...
29875-73-89H-Tribenzo[b,d,f]az...
Compound Q&A
How is 1-Cyclopropyl-7-ethoxy-6-fluoro-8-methoxy-4-oxo-1,4-dihydro-3-quinolinecarboxylic acid (CAS: 1797982-51-4) typically synthesized?
1-Cyclopropyl-7-ethoxy-6-fluoro-8-methoxy-4-oxo-1,4-dihydro-3-quinolinecarboxyli...
1797982-51-41-Cyclopropyl-7-etho...
Compound Q&A
How should waste containing Methyl 3-oxo-1,2,3,4-tetrahydro-6-quinoxalinecarboxylate (CAS: 671820-52-3) be handled?
Waste containing Methyl 3-oxo-1,2,3,4-tetrahydro-6-quinoxalinecarboxylate (CAS: ...
671820-52-3Methyl 3-oxo-1,2,3,4...
Source Journal
Analyst
CiteScore:
7.8
Self-citation Rate:
5.6%
Articles per Year:
653
Analyst publishes analytical and bioanalytical research that reports premier fundamental discoveries and inventions, and the applications of those discoveries, unconfined by traditional discipline barriers.
Recommended Compounds
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.